1420537-56-9

Basic information

• Product Name: Ir(4,4’-di-tert-butyl-2,2’-bipyridyl)(4-methoxy-2-methylphenyl)₃
• CAS NO: 1420537-56-9
• Molecular Weight: 824.099
• Mol File: 1420537-56-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ir(4,4’-di-tert-butyl-2,2’-bipyridyl)(4-methoxy-2-methylphenyl)₃(CAS DataBase Reference)
• NIST Chemistry Reference: Ir(4,4’-di-tert-butyl-2,2’-bipyridyl)(4-methoxy-2-methylphenyl)₃(1420537-56-9)
• EPA Substance Registry System: Ir(4,4’-di-tert-butyl-2,2’-bipyridyl)(4-methoxy-2-methylphenyl)₃(1420537-56-9)

Safety Data

• Hazardous Substances Data: 1420537-56-9(Hazardous Substances Data)

Upstream product

• 148706-30-3 2-methyl-4-methoxyphenylmagnesium bromide 

Relevant articles and documents

Reactions of a ruthenium(VI) nitride with rhodium(III) and iridium(III) aryl complexes. Insertion of the Ru≡N group into the Rh-C bonds of trimesitylrhodium(III)

The reaction of the RuVI nitride LOEtRu VI(N)Cl2 (1; LOEt- = [Co(η5-C5H5){P(O)(OEt)2} 3]-) with RhIII(mes)3 (mes = mesityl) results in insertion of the Ru≡N group into the Rh-C bonds and formation of trinuclear (LOEt)ClRuIV(μ-Cl)(μ-2- CH2-4,6-Me2C6H2N)Rh III(μ-Nmes)(μ-Cl)2RuIV(LOEt) (2), containing a cyclometalated μ-mesitylimido ligand, whereas that with IrIII(dtbpy)R3 gives the μ-nitrido complexes (dtbpy)R3IrIII(μ-N)RuIVCl2(L OEt) (dtbpy = 4,4′-di-tert-butyl-2,2′-bipyridyl; R = 2,5-dimethylphenyl (3), 4-methoxy-2-methylphenyl (4)). The crystal structures of 2 and 4 have been determined.