142070-82-4

Basic information

• Product Name: Benzene, 1-(azidomethyl)-4-(methylthio)-
• CAS NO: 142070-82-4
• Molecular Formula: C8H9N3S
• Molecular Weight: 179.246
• Mol File: 142070-82-4.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(azidomethyl)-4-(methylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(azidomethyl)-4-(methylthio)-(142070-82-4)
• EPA Substance Registry System: Benzene, 1-(azidomethyl)-4-(methylthio)-(142070-82-4)

Safety Data

• Hazardous Substances Data: 142070-82-4(Hazardous Substances Data)

Upstream product

• 3446-90-0 4-(methylthio)benzyl alcohol 
• 124-63-0 methanesulfonyl chloride 
• 874-87-3 1-(chloromethyl)-4-methylthiobenzene 
• 3446-89-7 4-(Methylthio)benzaldehyde 
• 38185-19-2 4-(methylthio)benzyl bromide 

Downstream Products

• 21382-98-9 p-cyanophenyl methyl sulfide 
• 15197-90-7 N,N-dimethyl-1-(4-(methylthio)phenyl)methanamine 
• 84212-03-3 4-(Methylthio)-N-methylbenzenemethanamine 
• 3446-89-7 4-(Methylthio)benzaldehyde 
• 1233082-98-8 C₂₃H₂₃N₃O₂S 
• 142070-83-5 4-[(chloromethyl)thio]benzylazide 

Relevant articles and documents

Carcarinic acid-1, 2, 3- based triazole compound as well as preparation method and application thereof (by machine translation)

The method comprises the following steps: firstly 1, 2, 3 - oxidizing and opening the carbon- carbon double bond of the, carcarinic acid into methylene to, obtain carcarinic acid (not shown, in the technical field of, organic 3 - synthesis), Wolf - Kishner - 1, 2, 3 - 1, 2, 3 - 1, 2, 3 - 3 . (by machine translation)

Selective synthesis of mono- and di-methylated amines using methanol and sodium azide as C1 and N1 sources

A Ru(ii) complex mediated synthesis of various N,N-dimethyl and N-monomethyl amines from organic azides using methanol as a methylating agent is reported. This methodology was successfully applied for a one-pot reaction of bromide derivatives and sodium azide in methanol. Notably, by controlling the reaction time several N-monomethylated and N,N-dimethylated amines were synthesized selectively. The practical applicability of this tandem process was revealed by preparative scale reactions with different organic azides and synthesis of an anti-vertigo drug betahistine. Several kinetic experiments and DFT studies were carried out to understand the mechanism of this transformation.

The Cu(i)-catalysed Huisgen 1,3-dipolar cycloaddition route to (bio-)organic functionalisation of polyoxovanadates

The [V6O13{(OCH2)3CCH2OCH2CCH}2]2- with two terminal alkyne functionalities exhibits excellent reactivity towards (bio-)organic azides. The designed synthetic protocol for the generation of triazol-modified Lindqvist hexavanadates grants access to bio-"clicked" polyoxometalates with spectroscopically detectable 51V nuclei.