142087-14-7

Basic information

• Product Name: 1-(2-methyl-benzyl)-1H-benzo[d][1,2,3]triazole
• Synonyms: 1-(2-methyl-benzyl)-1H-benzo[d][1,2,3]triazole
• CAS NO: 142087-14-7
• Molecular Weight: 223.277
• Mol File: 142087-14-7.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 1-(2-methyl-benzyl)-1H-benzo[d][1,2,3]triazole(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-methyl-benzyl)-1H-benzo[d][1,2,3]triazole(142087-14-7)
• EPA Substance Registry System: 1-(2-methyl-benzyl)-1H-benzo[d][1,2,3]triazole(142087-14-7)

Safety Data

• Hazardous Substances Data: 142087-14-7(Hazardous Substances Data)

Upstream product

• 54187-96-1 1-(chloromethyl)-1H-benzotriazole 
• 95-46-5 2-methylphenyl bromide 
• 95-14-7 1,2,3-Benzotriazole 
• 88284-48-4 2-(trimethylsilyl)phenyl trifluoromethanesulfonate 
• 126799-83-5 2-methylbenzylazide 
• 1334478-50-0 Br^(1-)*C₂₂H₂₂N₃⁽¹⁺⁾ 
• 89-92-9 2-methylbenzyl bromide 
• 552-45-4 1-chloromethyl-2-methylbenzene 

Downstream Products

• 196861-94-6 1-<1-(2-methylphenyl)-2-(trimethylsilyl)ethyl>-1H-1,2,3-benzotriazole 

Relevant articles and documents

A convenient way for alkylation of amines using xanthate esters

N-alkylation of amines by the reaction with xanthate esters in the presence of acetic acid catalyst in ethanol is reported. Short reaction time, high yield, general applicability and environmentally benign nature are the noteworthy features of our protocol. The probable mechanism for the formation N-alkylation of amines is proposed.

Synthesis of 1,2,3-Triarylpyrroles from 1-Benzylbenzotriazoles via [1 + 2 + 2] Annulation

1,2,3-Triarylpyrroles 7 have been synthesized by sequential lithiation and alkylation of 1-benzylbenzotriazoles 1 with 2-bromoacetaldehyde diethyl acetal (2) and N-benzylideneaniline (4), followed by treatment with formic acid in ethanol.

Convenient and stereoselective synthesis of symmetrical (E)-stilbenes via homocoupling of 1,3-dibenzylbenzotriazolium bromides

Using NaH as the base and DMSO as the solvent, a series of symmetric (E)-stilbenes were prepared in good yields via the -homocoupling of 1,3-dibenzylbenzotriazolium bromides at room temperature. Georg Thieme Verlag Stuttgart · New York.