1421057-42-2

Basic information

• Product Name: [Cu(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)(4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)](PF₆)
• Synonyms: [Cu(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)(4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)](PF₆)
• CAS NO: 1421057-42-2
• Molecular Weight: 1147.6
• Mol File: 1421057-42-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: [Cu(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)(4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)](PF₆)(CAS DataBase Reference)
• NIST Chemistry Reference: [Cu(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)(4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)](PF₆)(1421057-42-2)
• EPA Substance Registry System: [Cu(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)(4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)](PF₆)(1421057-42-2)

Safety Data

• Hazardous Substances Data: 1421057-42-2(Hazardous Substances Data)

Upstream product

• 64443-05-6 tetrakis(actonitrile)copper(I) hexafluorophosphate 
• 4733-39-5 Bathocuproine 
• 161265-03-8 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene 

Relevant articles and documents

Heteroleptic copper(I) complexes as energy transfer photocatalysts for the intermolecular [2 + 2] photodimerization of chalcones, cinnamates and cinnamamides

The [2 + 2] photodimerization of chalcones, cinnamates and cinnamamides can be effectively catalyzed by heteroleptic copper(I) complexes. The reactions were carried out under mild reaction conditions and the products were obtained in 20–72% yield under visible light irradiation. The copper-based photocatalyst comprised of the rigid phenanthroline ligand with substituents at the 2,9-positions and the 4,7-positions showed high activity in the photodimerization via an energy transfer pathway.

Photocatalytic water reduction with copper-based photosensitizers: A noble-metal-free system

Of noble descent: A fully noble-metal-free system for the photocatalytic reduction of water at room temperature has been developed. This system consists of CuI complexes as photosensitizers and [Fe3(CO) 12] as the water-reduction catalyst. The novel Cu-based photosensitizers are relatively inexpensive, readily available from commercial sources, and stable to ambient conditions, thus making them an attractive alternative to the widely used noble-metal based systems.