1421281-40-4

Basic information

• Product Name: 1-methyl-2-phenyl-5,6-dihydro-4H-pyrrolo[3,2,1-ij]quinoline
• Synonyms: 1-methyl-2-phenyl-5,6-dihydro-4H-pyrrolo[3,2,1-ij]quinoline
• CAS NO: 1421281-40-4
• Molecular Weight: 247.34
• Mol File: 1421281-40-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-methyl-2-phenyl-5,6-dihydro-4H-pyrrolo[3,2,1-ij]quinoline(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methyl-2-phenyl-5,6-dihydro-4H-pyrrolo[3,2,1-ij]quinoline(1421281-40-4)
• EPA Substance Registry System: 1-methyl-2-phenyl-5,6-dihydro-4H-pyrrolo[3,2,1-ij]quinoline(1421281-40-4)

Safety Data

• Hazardous Substances Data: 1421281-40-4(Hazardous Substances Data)

Upstream product

• 673-32-5 1-Phenylprop-1-yne 
• 5825-45-6 1-amino-1,2,3,4-tetrahydroquinoline 

Relevant articles and documents

A Versatile, Traceless C-H Activation-Based Approach for the Synthesis of Heterocycles

A versatile, traceless C-H activation-based approach for the synthesis of diversified heterocycles is reported. Rh(III)-catalyzed, N-amino-directed C-H alkenylation generates either olefination products or indoles (in situ annulation) in an atom- and step-economic manner at room temperature. The remarkable reactivity endowed by this directing group enables scale-up of the reaction to a 10 g scale at a very low catalyst loading (0.01 mol %/0.1 mol %). Ex situ annulation of olefination product provides entry into an array of heterocycles.

Zirconium hydrazinediido complexes derived from cyclic hydrazines and their role in the catalytic synthesis of 1,7-annulated indoles

Reaction of cyclic 1,1′-disubstituted hydrazines with the bis(dimethylamido)zirconium complex [Zr{(NXyl)2N py} (NMe2)2] (1) in the presence of dmap yielded the hexacoordinate zirconium hydrazinediido