142207-36-1

Basic information

• Product Name: 2-(2,6-dideuterophenyl)pyridine
• Synonyms: 2-(2,6-dideuterophenyl)pyridine
• CAS NO: 142207-36-1
• Molecular Weight: 157.183
• Mol File: 142207-36-1.mol
• Article Data: 54

Chemical Properties

• CAS DataBase Reference: 2-(2,6-dideuterophenyl)pyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2,6-dideuterophenyl)pyridine(142207-36-1)
• EPA Substance Registry System: 2-(2,6-dideuterophenyl)pyridine(142207-36-1)

Safety Data

• Hazardous Substances Data: 142207-36-1(Hazardous Substances Data)

Upstream product

• 1008-89-5 2-phenylpyridine 
• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 23860-35-7 cyclohexylacetic acid chloride 
• 98-80-6 phenylboronic acid 
• 17508-16-6 tert-butyl (2,4-dinitrophenoxy)carbamate 
• 109-04-6 2-bromo-pyridine 
• 55305-43-6 N-cyano-N-phenyl-p-toluenesulfonamide 
• 897440-09-4 2-(2,6-dibromophenyl)pyridine 
• 70-55-3 toluene-4-sulfonamide 
• 98-88-4 benzoyl chloride 
• 6750-04-5 propargyl benzoate 
• 1421006-89-4 prop-2-yn-3-D-1-yl benzoate 
• 1404120-26-8 naphthalen-1-yl(2-(pyridin-2-yl)phenyl)methanol 
• 94-41-7 benzalacetophenone 

Downstream Products

• 1190991-82-2 ²H-2-(pyridin-2-yl)benzonitrile 
• 1401251-47-5 2-(pyridin-2-yl)isophthalonitrile 
• 1452876-71-9 C₁₁H₈⁽²⁾HNO 
• 1064604-91-6 2-(2,6-dicyclooctylphenyl)pyridine 

Relevant articles and documents

Application of iridium pincer complexes in hydrogen isotope exchange reactions

Iridium pincer complex catalyzed hydrogen to deuterium exchange could be achieved using aromatic and heteroaromatic substrates. The reactions proceed under mild conditions and with high regioselectivity. The efficiency of the hydrogen isotope exchange rea

Deaminativemeta-C-H alkylation by ruthenium(ii) catalysis

Precise structural modifications of amino acids are of importance to tune biological properties or modify therapeutical capabilities relevant to drug discovery. Herein, we report a ruthenium-catalyzedmeta-C-H deaminative alkylation with easily accessible amino acid-derived Katritzky pyridinium salts. Likewise, remote C-H benzylations were accomplished with high levels of chemoselectivity and remarkable functional group tolerance. Themeta-C-H activation approach combined with our deaminative strategy represents a rare example of selectively converting C(sp3)-N bonds into C(sp3)-C(sp2) bonds.

Traceless-Activation Strategy for Rh-Catalyzed Csp2-H Arylation of Coumarins

A traceless-activation strategy for the synthesis of 4-arylchroman-2-ones via a Rh(III)-catalyzed C-H activation of 2-arylpyridines and subsequent conjugated/decarboxylative addition to coumarin-3-carboxylic acids has been reported. The carboxyl group at

Regioselective ruthenium catalysed H-D exchange using D2O as the deuterium source

An efficient and convenient ruthenium catalysed method for a regiospecific H/D exchange using D2O is described. Organic moieties such as pyridine, oxazole, imidazole, pyrazole, ester, ketone and carboxylic acid have been found effective directing groups in this transformation. In addition, the deuteration of the enantiopure (S)-Ketoprofen leads to the incorporation of three deuterium atoms with retention of molecular chirality.

Iridium(I) Complexes with Anionic N-Heterocyclic Carbene Ligands as Catalysts for H/D Exchange in Nonpolar Media

A series of neutral iridium(I) complexes of the general type [(WCA?NHC)]IrL(COD)] (COD=1,5-cyclooctadiene; L=phosphine, pyridine), bearing anionic N-heterocyclic carbenes (WCA?NHC) with a weakly coordinating anionic (WCA) borate moiety, were prepared by a

Parallel chemistry investigations of ortho-directed hydrogen isotope exchange between substituted aromatics and isotopic water: Novel catalysis by cyclooctadienyliridium(I)pentan-1,3-dionates

Novel iridium-based catalysts which promote ortho-directed hydrogen isotope exchange between substituted aromatics and isotopic water have been identified via a combination of screening and subsequent ligand optimisation. The catalysts are more active, op

Capturing Elusive Cobaltacycle Intermediates: A Real-Time Snapshot of the Cp*CoIII-Catalyzed Oxidative Alkyne Annulation

Despite Cp*CoIII catalysts having emerged as a very attractive alternative to noble transition metals for the construction of heterocyclic scaffolds through C?H activation, the structure of the reactive species remains uncertain. Herein, we rep

Mild, Selective Ru-Catalyzed Deuteration Using D2O as a Deuterium Source

A method for the selective deuteration of polyfunctional organic molecules using catalytic amounts of [RuCl2(PPh3)3] and D2O as a deuterium source is presented. Through variation of additives like CuI, KOH, and various amounts of zinc powder, orthogonal chemoselectivities in the deuteration process are observed. Mechanistic investigation indicates the presence of different, defined Ru-complexes under the given specific conditions.