142329-94-0

Basic information

• Product Name: 4-nitrophenyl 2-acetamido-2-deoxy-4,6-O-isopropylidene-β-D-glucopyranoside
• Synonyms: 4-nitrophenyl 2-acetamido-2-deoxy-4,6-O-isopropylidene-β-D-glucopyranoside
• CAS NO: 142329-94-0
• Molecular Weight: 382.37
• Mol File: 142329-94-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-nitrophenyl 2-acetamido-2-deoxy-4,6-O-isopropylidene-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 4-nitrophenyl 2-acetamido-2-deoxy-4,6-O-isopropylidene-β-D-glucopyranoside(142329-94-0)
• EPA Substance Registry System: 4-nitrophenyl 2-acetamido-2-deoxy-4,6-O-isopropylidene-β-D-glucopyranoside(142329-94-0)

Safety Data

• Hazardous Substances Data: 142329-94-0(Hazardous Substances Data)

Upstream product

• 7512-17-6 N-Acetyl-D-glucosamine 
• 100-02-7 4-nitro-phenol 
• 13089-27-5 p-nitrophenyl 2-acetamido-2-deoxy-3,4,6-tri-O-acetyl-β-D-glucopyranoside 
• 77-76-9 2,2-dimethoxy-propane 
• 3459-18-5 4-nitrophenyl N-acetyl-β-D-glucosaminide 

Downstream Products

• 142329-79-1 4-nitrophenyl O-<3,4-O-isopropylidene-2-O-(4-methoxybenzyl)-α-L-fucopyranosyl>-(1->3)-2-acetamido-2-deoxy-4,6-O-isopropylidene-β-D-glucopyranoside 
• 142329-80-4 4-nitrophenyl O-α-L-fucopyranosyl-(1->3)-2-acetamido-2-deoxy-β-D-glucopyranoside 
• 50271-46-0 4-nitrophenyl 2-acetamido-3-O-benzoyl-2-deoxy-β-D-glucopyranoside 
• 956011-72-6 4-nitrophenyl 2-acetamido-4-S-acetyl-3,6-di-O-benzoyl-2-deoxy-4-thio-β-D-glucopyranoside 
• 132498-72-7 4-nitrophenyl 2-acetamido-3,6-di-O-benzoyl-2-deoxy-β-D-glucopyranoside 
• 143535-88-0 C₄₂H₅₂N₂O₁₅ 

Relevant articles and documents

Syntheses of the 3- and 4-thio analogues of 4-nitrophenyl 2-acetamido-2-deoxy-β-d-gluco- and galactopyranoside

The syntheses of 4-nitrophenyl β-glycosides of the 3-thio and 4-thio analogues of the two principal 2-acetamido-2-deoxy-hexoses found in living systems, GlcNAc and GalNAc, are described. While synthesis of the 4-thio analogues could be achieved via nucleophilic displacements of sulfonate derivatives with thioacetate, problems with neighbouring group acetamido participation necessitated the use of sulfamidate intermediates for the 3-thio analogues. These 3- and 4-thio analogues are employed in the chemo-enzymatic synthesis of thio-oligosaccharide analogues of structures present in glycosaminoglycans, glycoproteins and glycolipids.