142344-35-2

Basic information

• Product Name: Silane, dichloro(3-methoxyphenyl)propyl-
• CAS NO: 142344-35-2
• Molecular Formula: C10H14Cl2OSi
• Molecular Weight: 249.212
• Mol File: 142344-35-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silane, dichloro(3-methoxyphenyl)propyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, dichloro(3-methoxyphenyl)propyl-(142344-35-2)
• EPA Substance Registry System: Silane, dichloro(3-methoxyphenyl)propyl-(142344-35-2)

Safety Data

• Hazardous Substances Data: 142344-35-2(Hazardous Substances Data)

Upstream product

• 2398-37-0 3-methoxyphenyl bromide 
• 141-57-1 n-propyltrichlorosilane 

Downstream Products

• 109251-88-9 3-Methoxyphenyl 1-naphthyl ketone 
• 126485-58-3 3'-methoxy-[1,1'-biphenyl]-3-carboxaldehyde 
• 27331-43-7 1-(3-methoxybiphenyl)naphthalene 
• 126485-53-8 (difluoro)(3-methoxyphenyl)(n-propyl)silane 

Relevant articles and documents

CARBONYLATIVE COUPLING REACTION OF ORGANOFLUOROSILANES WITH ORGANIC HALIDES PROMOTED BY FLUORIDE ION AND PALLADIUM CATALYST

Palladium-catalyzed carbonylative cross coupling reaction of organofluorosilanes with organic halides was achieved in the presence of fluoride ion and an atmospheric pressure of carbon monoxide.Alkenyl- or arylfluorosilanes effectively underwent this reaction with alkenyl or aryl iodides in moderate to good yields.Thus, highly functionalized ketones are readily available without protection of reactive functional group such as aldehyde, ketone, ester, nitril, and alcohol.For smooth ketone formation, use of organofluorosilanes is essential; tetraorganosilanes like aryl(trimethyl)silanes, upon reaction with aryl iodides, gave aroyl fluorides instead. Key Words: carbonylative coupling; organofluorosilanes; ketone synthesis