1424016-57-8

Basic information

• Product Name: (3,6-dibromopyridazin-4-yl)(phenyl)methanone
• Synonyms: (3,6-dibromopyridazin-4-yl)(phenyl)methanone
• CAS NO: 1424016-57-8
• Molecular Weight: 341.989
• Mol File: 1424016-57-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3,6-dibromopyridazin-4-yl)(phenyl)methanone(CAS DataBase Reference)
• NIST Chemistry Reference: (3,6-dibromopyridazin-4-yl)(phenyl)methanone(1424016-57-8)
• EPA Substance Registry System: (3,6-dibromopyridazin-4-yl)(phenyl)methanone(1424016-57-8)

Safety Data

• Hazardous Substances Data: 1424016-57-8(Hazardous Substances Data)

Upstream product

• 17973-86-3 3,6-dibromopyridazine 
• 98-88-4 benzoyl chloride 

Downstream Products

• 1424017-07-1 (3,6-dibromo-5-iodopyridazin-4-yl)(phenyl)methanone 
• 1424017-38-8 5-bromo-3-phenyl-1H-pyrazolo[3,4-c]pyridazine 
• 1424017-13-9 (5-benzoyl-3,6-dibromopyridazin-4-yl)(furan-2-yl)methanone 
• 1424017-04-8 (3,6-dibromo-5-(cyclohex-2-en-1-yl)pyridazin-4-yl)(phenyl)methanone 
• 1424017-10-6 1-(5-benzoyl-3,6-dibromopyridazin-4-yl)-2,2-dimethylpropan-1-one 
• 1424017-24-2 (3-bromo-6-(oct-1-yn-1-yl)pyridazin-4-yl)phenylmethanone 

Relevant articles and documents

New preparation of TMPZnCl·LiCl by Zn insertion into TMPCl. Application to the functionalization of dibromodiazines

A practical zinc insertion starting from cheap commercial zinc powder and TMPCl (1-chloro-2,2,6,6-tetramethylpiperidine) allows a fast and efficient synthesis of the zinc base TMPZnCl·LiCl under mild conditions in high yields. This base is kinetically highly active and was used for the regio- and chemoselective functionalization of dibromodiazines (pyridazines and pyrazines).