142505-40-6

Basic information

• Product Name: N-(3-nitrophenylmethylene)-2-methylthiobenzenamine
• Synonyms: N-(3-nitrophenylmethylene)-2-methylthiobenzenamine
• CAS NO: 142505-40-6
• Molecular Weight: 272.327
• Mol File: 142505-40-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(3-nitrophenylmethylene)-2-methylthiobenzenamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(3-nitrophenylmethylene)-2-methylthiobenzenamine(142505-40-6)
• EPA Substance Registry System: N-(3-nitrophenylmethylene)-2-methylthiobenzenamine(142505-40-6)

Safety Data

• Hazardous Substances Data: 142505-40-6(Hazardous Substances Data)

Upstream product

• 2987-53-3 2-(Methylthio)aniline 
• 99-61-6 3-nitro-benzaldehyde 

Downstream Products

• 142505-35-9 N-(3-nitrophenylmethylene)-2-phenylthiobenzenamine 
• 22868-33-3 2-(3-nitrophenyl)benzothiazole 
• 99-61-6 3-nitro-benzaldehyde 
• 142505-43-9 (2-aminophenyl)thiomethyl isopropyl carbonate 
• 142505-44-0 <(2-(3-nitrophenyl)methylenamino)phenyl>thiomethyl isopropyl carbonate 

Relevant articles and documents

The reaction of (2-alkylidenaminophenyl)sulfides with di-iso-propyl peroxydicarbonate: Radical versus non-radical pathway

The reaction of 2-methylthio- or 2-phenylthioarylimines with di-iso-propyl peroxydicarbonate (DPDC) is described. The phenylthio-derivatives undergo cyclization to benzothiazoles via a free-radical mechanism, whereas the methylthio-analogs afford arylthiomethyl iso-propyl carbonates, together with benzothiazoles as well; this last result could be accounted for with the intervention of a non-radical mechanism operating side by side with the radical one.