1426343-73-8

Basic information

• Product Name: C₂₀H₂₆ClGeN₂O⁽¹⁺⁾*Cl₃Ge^(1-)
• CAS NO: 1426343-73-8
• Molecular Weight: 597.431
• Mol File: 1426343-73-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₀H₂₆ClGeN₂O⁽¹⁺⁾*Cl₃Ge^(1-)(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₀H₂₆ClGeN₂O⁽¹⁺⁾*Cl₃Ge^(1-)(1426343-73-8)
• EPA Substance Registry System: C₂₀H₂₆ClGeN₂O⁽¹⁺⁾*Cl₃Ge^(1-)(1426343-73-8)

Safety Data

• Hazardous Substances Data: 1426343-73-8(Hazardous Substances Data)

Upstream product

• 1426343-78-3 C₂₀H₂₆N₂O 
• 24544-04-5 2,6-diisopropylbenzenamine 
• 21190-93-2 1-(6-methoxypyridin-2-yl)ethan-1-one 

Relevant articles and documents

Stabilization of three-coordinated germanium(II) and tin(II) cations by a neutral chelating ligand

Treatment of the neutral 2-[C(CH3)=N(C6H 3-2,6-iPr2)]-6-(CH3O)C 6H3N ligand (hereafter assigned as L) with SnCl 2 and GeCl2 provided the ionic germanium(II) and tin(II) complexes [LGeIICl]+[GeIICl3] - (1) and [LSnIICl]+[SnIICl 3]- (2), respectively, as the result of spontaneous dissociation of ECl2 (E = Ge, Sn). The cationic parts [LE IICl]+ of 1 and 2 contain three-coordinated germanium(II) and tin(II) atoms. In comparison, treatment of the ligand L with GeCl 4 and SnBr4 yielded the germanium(IV) and tin(IV) complexes LGeCl4 (3) and LSnBr4 (4), respectively, and no dissociation process was observed. Compounds 1-4 were characterized by means of elemental analyses, 1H, 13C, and 119Sn NMR spectroscopies, and single-crystal X-ray diffraction analysis in (compounds 1 and 4).