142742-42-5

Basic information

• Product Name: (2R,3S)-cis-6-chloro-3-dimethyl(1,1,2-trimethylpropyl)siloxy-1-vinylcyclohexa-4,6-diene-2-ol
• CAS NO: 142742-42-5
• Molecular Weight: 314.928
• Mol File: 142742-42-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,3S)-cis-6-chloro-3-dimethyl(1,1,2-trimethylpropyl)siloxy-1-vinylcyclohexa-4,6-diene-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3S)-cis-6-chloro-3-dimethyl(1,1,2-trimethylpropyl)siloxy-1-vinylcyclohexa-4,6-diene-2-ol(142742-42-5)
• EPA Substance Registry System: (2R,3S)-cis-6-chloro-3-dimethyl(1,1,2-trimethylpropyl)siloxy-1-vinylcyclohexa-4,6-diene-2-ol(142742-42-5)

Safety Data

• Hazardous Substances Data: 142742-42-5(Hazardous Substances Data)

Upstream product

• 2039-87-4 2-chlorostyrene 
• 67373-56-2 chlorodimethyl(1,1,2-trimethylpropyl)silane 

Relevant articles and documents

New Diol Metabolites Derived by Biooxidation of Chlorostyrenes with Pseudomonas putida: Determination of Absolute Stereochemistry and Enantiomeric Excess by Convergent Syntheses

The three isomers of chlorostyrenes were subjected to whole cell biooxidation by means of a mutant strain of Pseudomonas putida 39D.The metabolites were isolated and their absolute stereochemistry determined by conversion to known standards derived from 1-ethenyl-2,3-dihydroxycyclohexa-4,6-diene whose absolute configuration has been previously established.The extent of ring vs side chain oxidation of the chlorostyrene isomers was evaluated and the enantiomeric excess determined for all compounds.