142819-34-9Relevant articles and documents
Anionic Cycloaddition with Thiophthalides: an Integrated Approach to the Synthesis of Olivin and Pillaromycinone
Majumdar, Gita,Pal, Ranjan,Murty, Kadiyala V. S. N.,Mal, Dipakranjan
, p. 309 - 316 (2007/10/02)
A systematic study of the potential reactivity of the thiophthalides 4 and 18 - 20 as 1,4-dipolar synthons, has shown that 3-phenylthiothiophthalide 19 is the best annulating agent for the preparation of tricyclic intermediates related to olivin.The reagent 19 underwent anionic cycloaddition with cyclohex-2-enone 5a in the presence of lithium tert-butoxide to give the anthracenones 24a and 25 in a combined yield of 90percent.