1428246-15-4

Basic information

• Product Name: C₁₅H₂₄O₃S₂
• Synonyms: C₁₅H₂₄O₃S₂
• CAS NO: 1428246-15-4
• Molecular Weight: 316.486
• Mol File: 1428246-15-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₅H₂₄O₃S₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₅H₂₄O₃S₂(1428246-15-4)
• EPA Substance Registry System: C₁₅H₂₄O₃S₂(1428246-15-4)

Safety Data

• Hazardous Substances Data: 1428246-15-4(Hazardous Substances Data)

Upstream product

• 5577-44-6 2,4-octadien-1-al 
• 69443-04-5 1-Ethyl-2-isopropyl-1,1-dithiooxalat 

Relevant articles and documents

Asymmetric organocatalytic thio-diels-alder reactions via trienamine catalysis

We report a new process to access highly enantioenriched sulfur-based heterocycles by an asymmetric catalytic thio-Diels-Alder reaction. Thiocarbonyls are challenging heterodienophiles in enantioselective Diels-Alder reactions, due to their inherent high reactivity and their poor ability to coordinate to chiral catalysts. We successfully circumvented these problems by employing a different strategy, which explores the use of in situ generated catalyst-bound dienes. Synthetically useful dihydrothiopyrans as well as other bi- and tricyclic sulfur-containing heterocycles are formed in high yields and high to excellent selectivities. DFT calculations were performed to examine the mechanism of the developed reaction. Furthermore, a series of synthetic transformations of the optically active sulfur-based heterocycles are presented.