1428321-23-6

Basic information

• Product Name: 5-methoxy-1,3-dehydroadamantane
• CAS NO: 1428321-23-6
• Molecular Weight: 164.247
• Mol File: 1428321-23-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 5-methoxy-1,3-dehydroadamantane(CAS DataBase Reference)
• NIST Chemistry Reference: 5-methoxy-1,3-dehydroadamantane(1428321-23-6)
• EPA Substance Registry System: 5-methoxy-1,3-dehydroadamantane(1428321-23-6)

Safety Data

• Hazardous Substances Data: 1428321-23-6(Hazardous Substances Data)

Upstream product

• 768-90-1 1-Adamantyl bromide 
• 768-95-6 1-adamanthanol 
• 24569-89-9 1,3-dehydroadamantane 
• 1428321-17-8 1,3-dibromo-5-methoxyadamantane 
• 6221-74-5 1-methoxyadamantane 

Relevant articles and documents

Synthesis of 1,3-dehydroadamantanes possessing alkyl, phenyl, and alkoxy substituents by intramolecular wurtz-type coupling reaction of 1,3-dibromoadamantanes

A series of highly strained [3.3.1]propellane derivatives, 1,3-dehydroadamantanes (DHAs) possessing alkyl, phenyl, and alkoxy substituents, such as 5-butyl, 5-hexyl, 5-octyl, 5-phenyl, 5-methoxy, 5-butoxy, 5,7-dimethyl, 5-ethyl-7-hexyl, 5,7-dibutyl-, 5-butyl-7-isobutyl, 5-butyl-7-hexyl, 5-butyl-7-phenyl, 5-butyl-7-methoxy, and 5-butoxy-7-butyl, were synthesized in several gram amounts. The 1,3-dibromoadamantanes carrying alkyl, phenyl, and alkoxy substituents were converted into the corresponding DHAs via the intramolecular Wurtz-type coupling reactions with lithium metal in THF in 21-81% yields. Georg Thieme Verlag Stuttgart . New York.