1428560-27-3Relevant articles and documents
Unexpected diels-Alder/carbonyl-ene cascade toward the biomimetic synthesis of chloropupukeananin
Suzuki, Takahiro,Miyajima, Yuria,Suzuki, Kaname,Iwakiri, Kanako,Koshimizu, Masaki,Hirai, Go,Sodeoka, Mikiko,Kobayashi, Susumu
, p. 1748 - 1751 (2013)
The biomimetic synthesis of the advanced model compound of chloropupukeananin has been achieved. The present synthesis features an unexpected enantiomer-differentiating Diels-Alder/carbonyl-ene cascade under high-pressure conditions and a base-promoted migration of the salicyl group.