1429638-49-2

Basic information

• Product Name: 5-((benzyloxy)methyl)-8,8,9,9-tetramethyl-5-(prop-1-en-2-yl)-2,4,7-trioxa-8-siladecane
• Synonyms: 5-((benzyloxy)methyl)-8,8,9,9-tetramethyl-5-(prop-1-en-2-yl)-2,4,7-trioxa-8-siladecane
• CAS NO: 1429638-49-2
• Molecular Weight: 380.6
• Mol File: 1429638-49-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5-((benzyloxy)methyl)-8,8,9,9-tetramethyl-5-(prop-1-en-2-yl)-2,4,7-trioxa-8-siladecane(CAS DataBase Reference)
• NIST Chemistry Reference: 5-((benzyloxy)methyl)-8,8,9,9-tetramethyl-5-(prop-1-en-2-yl)-2,4,7-trioxa-8-siladecane(1429638-49-2)
• EPA Substance Registry System: 5-((benzyloxy)methyl)-8,8,9,9-tetramethyl-5-(prop-1-en-2-yl)-2,4,7-trioxa-8-siladecane(1429638-49-2)

Safety Data

• Hazardous Substances Data: 1429638-49-2(Hazardous Substances Data)

Upstream product

• 158465-80-6 1-((tert-butyldimethylsilyl)oxy)-3-hydroxypropan-2-one 
• 1429638-47-0 1-(benzyloxy)-2-((tert-butyldimethylsilyloxy)methyl)-3-methylbut-3-en-2-ol 
• 150587-19-2 methoxymethoxy chloride 
• 1429638-46-9 2-(((tert-butyldimethylsilyl)oxy)methyl)-3-methylbut-3-ene-1,2-diol 

Downstream Products

• 1429638-39-0 4-(benzyloxy)-3-((tert-butyldimethylsilyloxy)methyl)-3-(methoxymethoxy)butan-2-one 

Relevant articles and documents

Diastereoselective synthesis of vicinal tertiary diols

A strategy for the synthesis of differentiated vicinal tertiary diols is described. The key step is a high-yielding, diastereoselective LaCl 3·2LiCl-mediated addition of a Grignard or organolithium reagent to ketone 2a. The reaction is believed to proceed via a 1,3-chelated intermediate. One of the adducts has been transformed into a functionalized cyclopentenone resembling the core structure of pactamycin.