143039-20-7Relevant articles and documents
Identification of a surface organometallic species anchored on a thiourea-functionalized silica xerogel. Crystal structure of the model compound [(μ-H)Ru3{μ3-SC(NHPr)NPh}(CO)9]
Boroni, Ermete,Predieri, Giovanni,Tiripicchio, Antonio,Camellini, Marisa Tiripicchio
, p. 3456 - 3458 (2008/10/08)
Ru3(CO)12 reacts with a thiourea-functionalized silica xerogel, derived from (EtO)3Si(CH2)3NHC(=S)NHPh, to give a tethered metal carbonyl cluster. This surface organometalic species has the same CO stretching pattern as that of the model compound [(μ-H)Ru3{μ3-SC-(NHPr)NPh}(CO)9] (1), obtained from the reaction of Ru3-(CO)12 with N-phenyl-N′-propylthiourea. The molecular structure of 1 has been fully elucidated by an X-ray diffraction study.