14310-29-3

Basic information

• Product Name: 1-nitro-4-phenethyl-benzene
• Synonyms: 1-nitro-4-phenethyl-benzene;1-(4-Nitrophenyl)-2-phenylethane;4-Nitrobibenzyl
• CAS NO: 14310-29-3
• Molecular Formula: C₁₄H₁₃NO₂
• Molecular Weight: 0
• Mol File: 14310-29-3.mol
• Article Data: 19

Chemical Properties

• Boiling Point: 347.4°Cat760mmHg
• Flash Point: 155°C
• Appearance: /
• Density: 1.166g/cm³
• Vapor Pressure: 0.000108mmHg at 25°C
• Refractive Index: 1.602
• CAS DataBase Reference: 1-nitro-4-phenethyl-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-nitro-4-phenethyl-benzene(14310-29-3)
• EPA Substance Registry System: 1-nitro-4-phenethyl-benzene(14310-29-3)

Safety Data

• Hazardous Substances Data: 14310-29-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H13NO2/c16-15(17)14-10-8-13(9-11-14)7-6-12-4-2-1-3-5-12/h1-5,8-11H,6-7H2

Upstream product

• 20264-95-3 2-(4-nitrophenyl)ethyl chloride 
• 1942-30-9 4-(phenylethynyl)nitrobenzene 
• 71-43-2 benzene 
• 143425-68-7 N-benzyl-N-4-nitrobenzyl-N'-methanesulfonylhydrazine 
• 103-29-7 1,1'-(1,2-ethanediyl)bisbenzene 
• 75-15-0 carbon disulfide 
• 7446-70-0 aluminium trichloride 
• 34420-17-2 (2-phenylethyl)boronic acid 
• 17763-80-3 para-nitrophenyl triflate 
• 586-78-7 para-nitrophenyl bromide 
• 1694-20-8 4-nitrostilbene 
• 100-14-1 4-nitrobenzyl chloride 
• 791020-40-1 N-benzyl-N-4-nitrobenzylhydrazine 
• 622-24-2 2-phenylethyl chloride 

Downstream Products

• 13024-49-2 4-aminodibenzyl 

Relevant articles and documents

Wilkinson's catalyst catalyzed selective hydrogenation of olefin in the presence of an aromatic nitro function: A remarkable solvent effect

Optimal conditions for chlorotris(triphenylphosphine)rhodium(I) (Wilkinson's catalyst) catalyzed selective saturation of a double bond in the presence of a nitro function are developed. Aryl iodide and benzyl ether are also tolerated under these hydrogenation conditions.

Bis(bipyridine) ruthenium(ii) bis(phosphido) metalloligand: Synthesis of heterometallic complexes and application to catalytic (E)-selective alkyne semi-hydrogenation

The first phosphido derivative of the bis(bipyridine) ruthenium(ii) fragment, cis-[(bpy)2Ru(PPh2)2] ([RuP2]), has been developed and applied as a P-donor metalloligand to form new Ru-Rh, Ru-Ir and Ru2Cu2 heterometallic complexes. The Ru-Ir hydride complex [([RuP2])IrH(NCMe)3][BF4]2 exhibits significant catalytic activity for (E)-selective semi-hydrogenation of alkynes.

Cobalt(II)-catalyzed preparation of alkylindium reagents and applications in cross-coupling with aryl halides

The direct insertion of indium powder into alkyl iodides was found to be efficiently catalyzed by a catalytic amount of cobalt(II) bromide (10 mol%). Upon subjection of the thus-formed alkylindium compounds to palladium-catalyzed cross-coupling reactions with a wide range of aryl halides, a series of cross-coupled products could be obtained in moderate to good yields with the tolerance to many important functional groups.