1432036-83-3

Basic information

• Product Name: C₃₉H₇₆N₄P₆Zr
• Synonyms: C₃₉H₇₆N₄P₆Zr
• CAS NO: 1432036-83-3
• Molecular Weight: 878.126
• Mol File: 1432036-83-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₃₉H₇₆N₄P₆Zr(CAS DataBase Reference)
• NIST Chemistry Reference: C₃₉H₇₆N₄P₆Zr(1432036-83-3)
• EPA Substance Registry System: C₃₉H₇₆N₄P₆Zr(1432036-83-3)

Safety Data

• Hazardous Substances Data: 1432036-83-3(Hazardous Substances Data)

Upstream product

• 81476-73-5 (cyclopentadienyl)(pentamethylcyclopentadienyl)zirconium dichloride 

Relevant articles and documents

Formation of polyphosphorus ligands mediated by zirconium and hafnium complexes

The reactions of R2P-P(SiMe3)Li (R = tBu, iPr, iPr2N) with [Cp2MCl 2] (M = Zr, Hf), [Cp*z.ast;CpZrCl2] and [CpZrCl 3] yielded polyphosphorus (mainly hexaphosphorus) compounds which can be viewed as intermediates between R2P-P(SiMe3)Li and derivatives of 1,2,3,4-tetraphosphabicyclo[1.1.0] butane. Thus R 2P-P(SiMe3)Li can act as a building block for the formation of the P2 ligand and the R2P-P(P2) and R2P-P(P2)P-PR2 moieties. Solid state structures of zirconium(IV) and hafnium(IV) complexes with R2P- P(P2) and R2P-P(P2)P-PR2 ligands were established by X-ray studies.