14324-99-3

Basic information

• Product Name: MN(TMHD)3
• Synonyms: MN(TMHD)3;TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)MANGANESE (III);Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese (III), (Mn(TMHD)3);TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)MANGANESE (III) 99% [MN(TMHD)3];Bis-(2,2,6,6-tetramethyl-3,5-heptandionato)manganese(II);Tris(2,2,6,6-tetramethyl-3,5-heptanedionate) manganese (III);Tris-(2,2,6,6-tetramethyl-3,5-heptanedionato-O,O'')-manganese;Bis-(2,2,6,6-tetramethyl-3,5-heptandionato)manganese(III)
• CAS NO: 14324-99-3
• Molecular Formula: C33H57MnO6
• Molecular Weight: 604.74
• Product Categories: metal beta-diketonate complexes;ALD Precursors
• Mol File: 14324-99-3.mol
• Article Data: 0

Chemical Properties

• Melting Point: 165°C
• Boiling Point: 255°C
• Appearance: black/crystal
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• CAS DataBase Reference: MN(TMHD)3(CAS DataBase Reference)
• NIST Chemistry Reference: MN(TMHD)3(14324-99-3)
• EPA Substance Registry System: MN(TMHD)3(14324-99-3)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39-36/37
• WGK Germany: 3
• Hazardous Substances Data: 14324-99-3(Hazardous Substances Data)

Usage

Description

MN(TMHD)3, also known as Tris(1,2,3-tetramethyl-4,5-dihydro-1H-1,2,4-triazol-3-yl)amine manganese(III), is a versatile and efficient catalyst with a unique structure. It possesses a strong ability to transfer electrons and has been found to be effective in various chemical reactions due to its unique properties.

Uses

Used in Chemical Synthesis:
MN(TMHD)3 is used as a catalyst for intramolecular Diels-Alder reactions, facilitating the formation of complex molecular structures with high selectivity and efficiency.
Used in DNA Research:
MN(TMHD)3 is used as a single electron donor for excess electron transfer studies in DNA, providing valuable insights into the electron transfer processes and their implications in DNA damage and repair mechanisms.
Used in Enantioselective Synthesis:
MN(TMHD)3 is used as a catalyst in enantioselective synthesis, enabling the production of chiral compounds with high enantiomeric excess, which is crucial for the development of pharmaceuticals and agrochemicals.
Used in Borylation Reactions:
MN(TMHD)3 is used as a catalyst in borylation reactions, promoting the formation of carbon-boron bonds, which are essential in the synthesis of various organic compounds and materials.
Used in Hydrohydrazination and Hydroazidation Reactions:
MN(TMHD)3 is used as a catalyst in hydrohydrazination and hydroazidation reactions, enabling the selective formation of hydrazides and amidrazones, which are important intermediates in the synthesis of pharmaceuticals and other organic compounds.
Used in Oxidative Carbonylation of Phenol:
MN(TMHD)3 is used as a catalyst in the oxidative carbonylation of phenol, leading to the production of valuable chemicals such as salicylic acid and its derivatives, which are widely used in the pharmaceutical and chemical industries.