143359-96-0

Basic information

• Product Name: Acetamide, N-(2-phenoxyphenyl)-
• CAS NO: 143359-96-0
• Molecular Formula: C14H13NO2
• Molecular Weight: 227.263
• Mol File: 143359-96-0.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Acetamide, N-(2-phenoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetamide, N-(2-phenoxyphenyl)-(143359-96-0)
• EPA Substance Registry System: Acetamide, N-(2-phenoxyphenyl)-(143359-96-0)

Safety Data

• Hazardous Substances Data: 143359-96-0(Hazardous Substances Data)

Upstream product

• 2216-12-8 1-nitro-2-phenoxy-benzene 
• 2688-84-8 2-phenoxyaniline 
• 1493-27-2 ortho-nitrofluorobenzene 
• 108-95-2 phenol 
• 95-55-6 2-amino-phenol 
• 614-80-2 2-(acetylamino)phenol 
• 577-19-5 2-nitrophenyl bromide 
• 75-36-5 acetyl chloride 
• 100-67-4 potassium phenolate 

Downstream Products

• 860570-81-6 acetic acid-(4-bromo-2-phenoxy-anilide) 
• 2172-84-1 acetic acid-(4-nitro-2-phenoxy-anilide) 
• 860577-76-0 acetic acid-[4-nitro-2-(4-nitro-phenoxy)-anilide] 
• 50548-37-3 N-(4-dibenzofuranyl)acetamide 
• 50548-45-3 1-bromodibenzo[b,d]furan 
• 162607-19-4 dibenzo[b,d]furan-1-yl-boronic acid 
• 65642-94-6 1-bromodibenzo[b,d]thiophene 

Relevant articles and documents

Metal-free formal synthesis of phenoxazine

A transition metal-free formal synthesis of phenoxazine is presented. The key step of the sequence is a high-yielding O-arylation of a phenol with an unsymmetrical diaryliodonium salt to provide an ortho-disubstituted diaryl ether. This species was cyclized to acetylphenoxazine in moderate yield. The overall yield in the three-step sequence is 72% based on recovered diaryl ether. An interesting, unusually stable iodine(III) intermediate in the O-arylation was observed by NMR and could be converted to the product upon longer reaction time.

Access to Chiral Seven-Member Cyclic Amines via Rh-Catalyzed Asymmetric Hydrogenation

A highly efficient asymmetric hydrogenation of azepine/oxazepine-type seven-member cyclic imine hydrochlorides was successfully developed using Rh/bisphosphine-thiourea ligand ZhaoPhos, affording various chiral seven-member cyclic amines with full conversions, high yields, and excellent enantioselectivities (up to 96% yield, >99% ee). Additionally, this asymmetric hydrogenation can proceed well on gram scale with excellent ee value. Moreover, control experimental results displayed that the anion-bonding interaction between the chloride ion of the substrate and thiourea motif of the ZhaoPhos played an important role to obtain excellent enantioselectivity.

PHOSPHORESCENT EMITTERS

Compounds including a ligand with a dibenzo-fused 5-membered ring substituent are provided. In particular, the compounds may be iridium complexes including imidazole coordinated to the dibenzo-substituted ligand. The dibenzo-fused 5-membered ring moiety of the ligand may be twisted or minimally twisted out of plane with respect to the rest of the ligand structure. The compound may be used in organic light emitting devices, particularly as emitting dopants in blue devices. Devices comprising the compounds may demonstrate improved stability while maintaining excellent color.