1437709-20-0

Basic information

• Product Name: (R)-2-(3-ethyl-6,6-dimethyl-1-phenylhept-4-yn-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• Synonyms: (R)-2-(3-ethyl-6,6-dimethyl-1-phenylhept-4-yn-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• CAS NO: 1437709-20-0
• Molecular Weight: 384.367
• Mol File: 1437709-20-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-2-(3-ethyl-6,6-dimethyl-1-phenylhept-4-yn-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-2-(3-ethyl-6,6-dimethyl-1-phenylhept-4-yn-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(1437709-20-0)
• EPA Substance Registry System: (R)-2-(3-ethyl-6,6-dimethyl-1-phenylhept-4-yn-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(1437709-20-0)

Safety Data

• Hazardous Substances Data: 1437709-20-0(Hazardous Substances Data)

Upstream product

• 76-09-5 2,3-dimethyl-2,3-butane diol 
• 10173-38-3 2-ethyl-1,3,2-dioxaborolane 
• 1437708-92-3 (S)-1-(4-methoxyphenyl)-6,6-dimethylhept-4-yn-3-yl-N,N-bis(propan-2-yl)carbamate 

Relevant articles and documents

Enantioselective synthesis and cross-coupling of tertiary propargylic boronic esters using lithiation-borylation of propargylic carbamates

Lithiation-borylation of propargylic carbamates leads to tertiary propargylic boronic esters in very high e.r., provided that ethylene glycol boronic esters are used. These versatile intermediates undergo a range of highly stereoselective transformations, including protodeboronation to give tertiary allenes and Suzuki-Miyaura cross-couplings of tertiary boron species leading to tetrasubstituted allenes with high enantiospecificity. Copyright