143876-42-0Relevant articles and documents
The Rotation-dominated Ring Inversion/Nitrogen Inversion/Rotation Process in N-Acyloxy-2,2,6,6-tetramethylpiperidines. A Dynamic NMR Study
Anderson, J. Edgar,Corrie, John E. T.
, p. 1027 - 1031 (2007/10/02)
The temperature dependence of the NMR spectra of a series of N-acyloxy-2,2,6,6-tetramethylpiperidines is reported and discussed in terms of a conformational process which involves ring inversion, nitrogen inversion and rotation about the nitrogen-oxygen bond.Nitrogen inversion contributes ca. 11 kcal mol-1 to the observed barriers, so in the compounds with higher barriers, steric interaction of the acyl and methyl groups during rotation determines the barrier height.