144121-61-9Relevant articles and documents
Highly efficient chemical kinetic resolution of bishomoallylic alcohols: Synthesis of (R)-sulcatol
Chen, Shui-Ling,Hu, Qi-Ying,Loh, Teck-Peng
, p. 3365 - 3367 (2004)
(Chemical Equation Presented) A highly efficient chemical kinetic resolution of bishomoallylic alcohols was developed when the alcohols underwent In(OTf)3-catalyzed 3,5-oxonium-ene-type cyclization with steroidal aldehyde 2. Consistently high e
Titanocene-catalyzed asymmetric ketone hydrosilylation: The effect of catalyst activation protocol and additives on the reaction rate and enantioselectivity
Yun, Jaesook,Buchwald, Stephen L.
, p. 5640 - 5644 (2007/10/03)
The efficient asymmetric hydrosilylation of ketones with a chiral titanocene catalyst has been realized. In this procedure, (R,R)-ethylenebis(tetrahydroindenyl) titanium difluoride (1) was used as the precatalyst, and alcohol additives were employed. Arom