144302-38-5

Basic information

• Product Name: (R)-benzylidene-(2-methoxy-1-phenylethyl)amine
• Synonyms: (R)-benzylidene-(2-methoxy-1-phenylethyl)amine
• CAS NO: 144302-38-5
• Molecular Weight: 239.317
• Mol File: 144302-38-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (R)-benzylidene-(2-methoxy-1-phenylethyl)amine(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-benzylidene-(2-methoxy-1-phenylethyl)amine(144302-38-5)
• EPA Substance Registry System: (R)-benzylidene-(2-methoxy-1-phenylethyl)amine(144302-38-5)

Safety Data

• Hazardous Substances Data: 144302-38-5(Hazardous Substances Data)

Upstream product

• 875-74-1 (R)-phenylglycine 
• 100-52-7 benzaldehyde 
• 64715-85-1 (R)-2-methoxy-1-phenylethylamine 

Downstream Products

• 144302-39-6 (1S,2S)-2-((R)-2-Methoxy-1-phenyl-ethylamino)-1,2-diphenyl-ethanol 
• 144254-13-7 (1R,2R)-2-((R)-2-Methoxy-1-phenyl-ethylamino)-1,2-diphenyl-ethanol 
• 144254-13-7 2-((S)-2-Methoxy-1-phenyl-ethylamino)-1,2-diphenyl-ethanol 
• 90933-77-0 <2-Methoxy-(R)-1-phenylethyl><(S)-1-phenylethyl>amine 
• 137038-55-2 (1R,1'R)-N-(2'-methoxy-1'-phenylethyl)-1-phenylethylamine 
• 144254-15-9 (S)-[(R)-2-methoxy-1-phenylethyl]-[(E)-1-phenyl-3-(trimethylsilyl)prop-2-enyl]amine 
• 144254-16-0 (R)-[(R)-2-methoxy-1-phenylethyl]-[(E)-1-phenyl-3-(trimethylsilyl)prop-2-enyl]amine 
• 566950-10-5 (R)-2-Phenyl-2-((R)-1-phenyl-buta-2,3-dienylamino)-ethanol 
• 566950-11-6 (+)-(R)-1-phenylbuta-2,3-dien-1-ylamine 
• 2941-19-7 (R)-1-phenylbutylamine 
• 944454-24-4 N-((1R,2R,5R)-5-hydroxy-2-methyl-1,7-diphenylheptyl)-2-nitrobenzenesulfonamide 
• 944454-22-2 N-((1S,2S,5R)-5-hydroxy-2-methyl-1,7-diphenylheptyl)-2-nitrobenzenesulfonamide 
• 944454-21-1 (3R,6R,7R)-7-amino-6-methyl-1,7-diphenylheptan-3-ol 

Relevant articles and documents

Chemoselective and stereoselective synthesis of gem-difluoro-β-aminoesters or gem-difluoro-β-lactams from ethylbromodifluoroacetate and imines during Reformatsky reaction

The chemoselective and stereoselective synthesis of gem-difluoro-β-aminoesters or gem-difluoro-β-lactams was investigated from ethylbromodifluoroacetate and imines during Reformatsky reaction. Influence of various reaction parameters, such as nature of the amine part, nature of the chiral auxiliary, was evaluated. High levels of stereoselectivity (up to 98%) were obtained for gem-difluoro-β-aminoesters and gem-difluoro-β-lactams using either (R)-phenylglycinol or (R)-methoxyphenylglycinol.

Enantioselective synthesis of diverse α-amino phosphonate diesters

An efficient, versatile protocol for the synthesis of highly enantioenriched α-amino phosphonate diesters has been devised. Addition of lithium diethyl phosphite to chiral chelating imines 31a-j, prepared from a variety of aldehydes and the chiral auxilia