144366-39-2

Basic information

• Product Name: Benzamide, N-methyl-2-nitroso-N-phenyl-
• CAS NO: 144366-39-2
• Molecular Formula: C14H12N2O2
• Molecular Weight: 240.261
• Mol File: 144366-39-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzamide, N-methyl-2-nitroso-N-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzamide, N-methyl-2-nitroso-N-phenyl-(144366-39-2)
• EPA Substance Registry System: Benzamide, N-methyl-2-nitroso-N-phenyl-(144366-39-2)

Safety Data

• Hazardous Substances Data: 144366-39-2(Hazardous Substances Data)

Upstream product

• 61899-13-6 N-methyl-N-phenyl-2-nitrobenzamide 

Downstream Products

• 118-92-3 anthranilic acid 
• 3342-77-6 N-formylanthranilic acid 
• 61899-13-6 N-methyl-N-phenyl-2-nitrobenzamide 
• 123534-30-5 1-(4'-methylphenylsulfonyl)-2,1-benzisoxazol-3(1H)-one 

Relevant articles and documents

Preparation and study of chemical transformations of N-formyl-N-phenylhydroxylamines

Nitrosobenzenes with CO2H 1b, CO2CH3 3b and CON(CH3)C6H5 4b ortho-substituents were obtained in a "redox" cell from the corresponding nitro compounds.In order to prepare the 3-oxo-1,2-dihydro-2,1-benzisoxazole-1-carbaldehyde from o-substituted N-formyl-N-phenylhydroxylamines, nitroso derivatives were formylated by glyoxylic acid.The N-formylbenzisoxazolone is unstable in the reaction medium and cannot be isolated.In addition to our study, we showed the unstability of N-formyl-N-phenylhydroxylamines and N-formylanilines in the presence of methanol without acetic acid; in an aqueous methanolic medium, formylation of nitrosoderivatives is equivalent to a reduction of the nitroso group.The mechanism was demonstrated by formylation of the nitrosobenzene and the electrogenerated 2-nitrosobenzene acetic acid 2b.Key Words: flow cell electrosynthesis / nitrosobenzenes / glyoxylic acid / formylation / N-formyl-N-phenylhydroxylamines / N-formylanilines / benzisoxazolones