144443-05-0

Basic information

• Product Name: Benzene, [(1-bromoethenyl)sulfinyl]-
• CAS NO: 144443-05-0
• Molecular Formula: C8H7BrOS
• Molecular Weight: 231.113
• Mol File: 144443-05-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, [(1-bromoethenyl)sulfinyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1-bromoethenyl)sulfinyl]-(144443-05-0)
• EPA Substance Registry System: Benzene, [(1-bromoethenyl)sulfinyl]-(144443-05-0)

Safety Data

• Hazardous Substances Data: 144443-05-0(Hazardous Substances Data)

Upstream product

• 20451-53-0 Phenyl vinyl sulfoxide 

Downstream Products

• 49833-32-1 1-phenyl-1-(phenylsulfinyl)-ethene 
• 1246377-22-9 1-bromo-2-[(1-phenylsulfinyl)vinyl]benzene 
• 1246377-20-7 1-(pivaloylamino) 2-[(1-phenylsulfinyl)vinyl]benzene 
• 1246377-16-1 1-trifluoromethyl-4-[(1-phenylsulfinyl)vinyl]benzene 
• 1246377-18-3 1-methoxy-2-[(1-phenylsulfinyl)vinyl]benzene 
• 1246377-21-8 1-trifluoromethyl-2-[(1-phenylsulfinyl)vinyl]benzene 
• 1246377-17-2 1-nitro-3-[(1-phenylsulfinyl)vinyl]benzene 
• 1202351-58-3 1-(4-methoxyphenyl)-1-(phenylsulfinyl)-ethene 
• 1246377-19-4 1-methyl-2-[(1-phenylsulfinyl)vinyl]benzene 
• 1246377-23-0 (E)-1(octa-1,3-dien-2-ylsulfinyl)benzene 
• 945-51-7 1,1'-sulfinylbisbenzene 
• 74-86-2 acetylene 

Relevant articles and documents

Efficient synthesis of racemic and chiral alkenyl sulfoxides by palladium-catalyzed Suzuki coupling

Alkenyl sulfoxide derivatives are obtained in high yields through a palladium-catalyzed Suzuki/Miyaura cross-coupling reaction of racemic and chiral 1-halo sulfoxides with aryl and alkenyl boronic acids. Chiral substrates react with no loss of optical purity and high optical yields. The reaction takes place with different palladium catalysts, such as Pd(PPh3)4 or Pd(OAc)2/DABCO. Although nitrogen ligands like DABCO lead to an active palladium catalyst, they are less effective than the phosphine ones.