1444611-61-3Relevant articles and documents
N-Iminopyridinium ylide-directed, cobalt-catalysed coupling of sp2C-H bonds with alkynes
Kwak, Se Hun,Daugulis, Olafs
, p. 11070 - 11073 (2020)
N-Iminopyridinium ylides are competent monodentate directing groups for cobalt-catalysed annulation of sp2C-H bonds with internal alkynes. The pyridine moiety in the ylide serves as an internal oxidant and is cleaved during the reaction. The annulation reactions possess excellent compatibility with heterocyclic substrates, tolerating furan, thiophene, pyridine, pyrrole, pyrazole, and indole functionalities.
Ruthenium-catalyzed aerobic oxidative cyclization of aromatic and heteroaromatic nitriles with alkynes: A new route to isoquinolones
Reddy, Mallu Chenna,Manikandan, Rajendran,Jeganmohan, Masilamani
supporting information, p. 6060 - 6062 (2013/07/19)
The oxidative cyclization of aromatic and heteroaromatic nitriles with alkynes in the presence of a catalytic amount of [{RuCl2(p-cymene)} 2], Cu(OAc)2·H2O and KPF6 in acetic acid under air gave isoquinolones in good to excellent yields.