14447-00-8

Basic information

• Product Name: prop-2-en-1-yl prop-2-ynoate
• Synonyms: 2-Propynoic acid, 2-propenyl ester; 2-Propynoic acid, 2-propenyl ester (9CI); Acetylenecarboxylic acid, allyl ester; Propiolic acid, allyl ester; Propiolic acid, allyl ester (8CI)
• CAS NO: 14447-00-8
• Molecular Formula: C₆H₆O₂
• Molecular Weight: 110.1106
• Mol File: 14447-00-8.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 150.5°C at 760 mmHg
• Flash Point: 42.9°C
• Density: 1.001g/cm³
• Vapor Pressure: 3.83mmHg at 25°C
• Refractive Index: 1.443
• CAS DataBase Reference: prop-2-en-1-yl prop-2-ynoate(CAS DataBase Reference)
• NIST Chemistry Reference: prop-2-en-1-yl prop-2-ynoate(14447-00-8)
• EPA Substance Registry System: prop-2-en-1-yl prop-2-ynoate(14447-00-8)

Safety Data

• Hazardous Substances Data: 14447-00-8(Hazardous Substances Data)

Upstream product

• 107-18-6 allyl alcohol 
• 471-25-0 Propiolic acid 
• 106-95-6 allyl bromide 

Downstream Products

• 102851-87-6 2-propenyl 5-(hydroxyphenylamino)-2-phenyl-4-<(2-propenyloxy)carbonyl>-3-isoxazolidineacetate 
• 1296885-37-4 (Z)-diallyl 2-{2-methoxy-2-[1-(4-methylbenzyl)-2-(p-tolyl)-1,2-dihydroquinolin-3-yl]vinyl}malonate 
• 1569639-93-5 (E)-2-((allyloxy)carbonyl)vinyl 2-iodobenzoate 

Relevant articles and documents

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Silica Gel as a Promoter of Sequential Aza-Michael/Michael Reactions of Amines and Propiolic Esters: Solvent- and Metal-Free Synthesis of Polyfunctionalized Conjugated Dienes

We present an efficient, simple, metal- and solvent-free silica-gel-promoted synthesis of functionalized conjugated dienes by sequential aza-Michael/Michael reactions by starting from commercially available primary amines and propiolic esters. The scope a

IMPROVED PREPARATION OF ALIPHATIC PROPYNOIC ESTERS

An improved procedure of esterification of propynoic acid, based on the N,N'-dicyclohexylcarbodiimide 4-dimethylaminopyridine condensation, is presented, which gives good results with primary, secondary, allylic and homoallylic alcohols.Reactions conditions are mild.Some limitations are given.