1445591-09-2Relevant articles and documents
Traceless chelation-controlled rhodium-catalyzed intermolecular alkene and alkyne hydroacylation
Hooper, Joel F.,Young, Rowan D.,Weller, Andrew S.,Willis, Michael C.
supporting information, p. 3125 - 3130 (2013/03/28)
A new functional-group tolerant, rhodium-catalyzed, sulfide-reduction process is combined with rhodium-catalyzed chelation-controlled hydroacylation reactions to give a traceless hydroacylation protocol. Aryl- and alkenyl aldehydes can be combined with both alkenes, alkynes and allenes to give traceless products in high yields. A preliminary mechanistic proposal is also presented. Traceless catalysis: The powerful combination of a chelation-controlled hydroacylation process and a new rhodium-catalyzed sulfide reduction gave the products of traceless hydroacylation. Aryl- and alkenyl aldehydes can be combined with alkenes, alkynes, and allenes to deliver traceless products in high yields (see scheme). Copyright
