1445784-01-9

Basic information

• Product Name: 2-maleimidoethyl 2-chloro-2-phenylacetate
• Synonyms: 2-maleimidoethyl 2-chloro-2-phenylacetate
• CAS NO: 1445784-01-9
• Molecular Weight: 293.707
• Mol File: 1445784-01-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-maleimidoethyl 2-chloro-2-phenylacetate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-maleimidoethyl 2-chloro-2-phenylacetate(1445784-01-9)
• EPA Substance Registry System: 2-maleimidoethyl 2-chloro-2-phenylacetate(1445784-01-9)

Safety Data

• Hazardous Substances Data: 1445784-01-9(Hazardous Substances Data)

Upstream product

• 1585-90-6 1-(2-hydroxyethyl)-1H-pyrrole-2,5-dione 
• 2912-62-1 α-chlorophenylacetyl chloride 

Relevant articles and documents

Periodically functionalized and grafted copolymers via 1:2-sequence- regulated radical copolymerization of naturally occurring functional limonene and maleimide derivatives

Naturally occurring hydroxy-functionalized limonene analogues, i.e., monoterpene alcohols such as perillyl alcohol and carveol, were radically copolymerized with cyclohexylmaleimide (CyMI) in PhC(CF3) 2OH via 1:2-sequence-regulated propagation to obtain periodically functionalized bio-based copolymers possessing one hydroxyl group in every three-monomer unit. Alternatively, a combination of hydroxy-functionalized maleimide (N-2-hydroxyethylmaleimide: HEMI) and limonene resulted in another periodically functionalized copolymer possessing two hydroxyl groups for every three-monomer unit. These copolymerizations were fitted well by the penultimate model, where the hydroxyl functions did not have a significant effect on the selective propagation, as has been reported for a combination of nonfunctionalized limonene and CyMI. The periodic hydroxyl groups can be quantitatively converted into carbamate moieties by a polymer reaction with isocyanate to result in another series of 1:2 and 2:1 periodically functionalized copolymers. Periodically grafted copolymers possessing one or two graft chains repeating in three-monomer units were prepared by radical copolymerization of chlorine-functionalized limonene or maleimide derivatives, which were synthesized from hydroxy-functionalized monomers, followed by ruthenium-catalyzed living radical polymerization of methyl methacrylate initiated from periodically introduced C-Cl bonds in the backbone copolymers.