144735-43-3

Basic information

• Product Name: (2S)-2-<(R)-1-(benzyloxy)-1-<(tert-butyldimethylsiloxy)methyl>ethyl>pyrrolidine
• Synonyms: (2S)-2-<(R)-1-(benzyloxy)-1-<(tert-butyldimethylsiloxy)methyl>ethyl>pyrrolidine
• CAS NO: 144735-43-3
• Molecular Weight: 349.589
• Mol File: 144735-43-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2S)-2-<(R)-1-(benzyloxy)-1-<(tert-butyldimethylsiloxy)methyl>ethyl>pyrrolidine(CAS DataBase Reference)
• NIST Chemistry Reference: (2S)-2-<(R)-1-(benzyloxy)-1-<(tert-butyldimethylsiloxy)methyl>ethyl>pyrrolidine(144735-43-3)
• EPA Substance Registry System: (2S)-2-<(R)-1-(benzyloxy)-1-<(tert-butyldimethylsiloxy)methyl>ethyl>pyrrolidine(144735-43-3)

Safety Data

• Hazardous Substances Data: 144735-43-3(Hazardous Substances Data)

Upstream product

• 153108-93-1 (2S)-N-<(benzyloxy)carbonyl>-2-<(R)-1-(benzyloxy)-1-formylethyl>pyrrolidine 
• 144735-42-2 (2S)-N-<(benzyloxy)carbonyl>-2-<(R)-1-(benzyloxy)-1-(hydroxymethyl)ethyl>pyrrolidine 
• 144735-40-0 (2S)-2-<(R)-1-(benzyloxy)-1-(dimethoxymethyl)ethyl>-N-(cyanomethyl)pyrrolidine 
• 153108-85-1 (2S)-2-<(R)-1-(benzyloxy)-1-(dimethoxymethyl)ethyl>pyrrolidine 
• 153108-84-0 (2S)-N-(cyanomethyl)-2-<(R)-1-(dimethoxymethyl)-1-hydroxyethyl>pyrrolidine 
• 144735-38-6 (2S)-2-<(R)-1-(1,3-dithian-2-yl)-1-hydroxyethyl>pyrrolidine 
• 144735-39-7 (2S)-2-<(R)-1-(dimethoxymethyl)-1-hydroxyethyl>pyrrolidine 
• 15761-39-4 1-(tert-butoxycarbonyl)-L-proline 
• 153108-94-2 (2S)-2-<(R)-1-(benzyloxy)-1-<(tert-butyldimethylsiloxy)methyl>ethyl>-N-<(benzyloxy)carbonyl>pyrrolidine 
• 120966-83-8 (S)-2-acetylpyrrolidine trifluoroacetate 
• 33857-76-0 Boc-proline 2-thiopyridyl ester 
• 91550-08-2 (S)-2-acetylpyrrolidine-1-carboxylic acid tert-butyl ester 

Downstream Products

• 144735-51-3 (2S)-2-<(R)-1-(benzyloxy)-1-<(tert-butyldimethylsiloxy)methyl>ethyl>-N-<(2E,6E)-(4R,8R,9R)-8,9-(isopropylidenedioxy)-4,7-dimethyl-2,6-decadien-1-yl>pyrrolidine 
• 153108-96-4 (7R,8R,8aS)-8-(benzyloxy)-7-hydroxy-8-methyl-6-(E)-<(2R,6R,7R)-6,7-dihydroxy-2,5-dimethyl-4-(E)-octenylidene>octahydroindolizidine 
• 144766-10-9 (7R,8R,8aS)-8-(benzyloxy)-7-hydroxy-6(Z)-<6(R),7(R)-(isopropylidenedioxy)-2(R),5-dimethyl-4(E)-octenylidene>-8-methyloctahydroindolizine 
• 153108-95-3 (2S)-2-<(R)-1-(benzyloxy)-1-(hydroxymethyl)ethyl>-N-<(2E,6E)-(4R,8R,9R)-8,9-(isopropylidenedioxy)-4,7-dimethyl-2,6-decadien-1-yl>pyrrolidine 
• 144735-52-4 (2S)-2-<(R)-1-(benzyloxy)-1-formylethyl>-N-<(2E,6E)-(4R,8R,9R)-8,9-(isopropylidenedioxy)-4,7-dimethyl-2,6-decadien-1-yl>pyrrolidine 

Relevant articles and documents

Highly stereoselective total syntheses of (+)-allopumiliotoxins 267A and 339A via intramolecular nickel(II)/chromium(II)-mediated cyclization

Remarkably high regio- and stereoselective approaches for the syntheses of dendrobatid alkaloids (+)allopumiliotoxin 267A and 339A have been develop. As a model study for these alkaloids, we initially undertook intramolecular chromium(II)-mediated cycliza