1447946-66-8Relevant articles and documents
Azaruthena(II)-bicyclo[3.2.0]heptadiene: Key Intermediate for Ruthenaelectro(II/III/I)-catalyzed Alkyne Annulations
Ackermann, Lutz,Finger, Lars H.,Kuniyil, Rositha,Messinis, Antonis M.,Scheremetjew, Alexej,Steinbock, Ralf,Yang, Long
supporting information, p. 11130 - 11135 (2020/05/18)
A ruthenium-catalyzed electrochemical dehydrogenative annulation reaction of imidazoles with alkynes has been established, enabling the preparation of various bridgehead N-fused [5,6]-bicyclic heteroarenes through regioselective electrochemical C?H/N?H annulation without chemical metal oxidants. Novel azaruthenabicyclo[3.2.0]heptadienes were fully characterized and identified as key intermediates. Mechanistic studies are suggestive of an oxidatively induced reductive elimination pathway within a ruthenium(II/III) regime.
Ruthenium-catalyzed benzimidazoisoquinoline synthesis via oxidative coupling of 2-arylbenzimidazoles with alkynes
Kavitha, Nerella,Sukumar, Genji,Kumar, Vemula Praveen,Mainkar, Prathama S.,Chandrasekhar, Srivari
, p. 4198 - 4201 (2013/07/26)
Synthesis of a fused bis-heterocyclic framework, benzimidazoisoquinoline, has been achieved using Ru-catalyzed reaction of alkynes with 2-aryl benzimidazoles in the presence of Cu salts. The method provides an easy access for the generation of a library of benzimidazoisoquinoline derivatives.