1447966-72-4

Basic information

• Product Name: (E)-1-(2-iodo-6-methylphenyl)-2-(2-o-tolyl)diazene
• Synonyms: (E)-1-(2-iodo-6-methylphenyl)-2-(2-o-tolyl)diazene
• CAS NO: 1447966-72-4
• Molecular Weight: 336.175
• Mol File: 1447966-72-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-1-(2-iodo-6-methylphenyl)-2-(2-o-tolyl)diazene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-(2-iodo-6-methylphenyl)-2-(2-o-tolyl)diazene(1447966-72-4)
• EPA Substance Registry System: (E)-1-(2-iodo-6-methylphenyl)-2-(2-o-tolyl)diazene(1447966-72-4)

Safety Data

• Hazardous Substances Data: 1447966-72-4(Hazardous Substances Data)

Upstream product

• 584-90-7 trans-di-o-tolyl-diazene 

Relevant articles and documents

Rh(iii)-Catalyzed regioselective mono- and di-iodination of azobenzenes using alkyl iodide

A new approach for highly regioselective iodination of azobenzenes with alkyl iodide as the iodinating reagent enabled by Rh-catalyzed oxidative C-H activation has been developed. By changing the oxidant, various mono- and di-iodinated azobenzenes were smoothly obtained in moderate to excellent yields, respectively. The preliminary mechanistic study reveals that the reaction process might undergo electrophilic substitution of the directed ortho metalated five-membered rhodacycle compound by an iodine cationic species generated in situ from alkyl iodide and oxidant.