1448422-99-8

Basic information

• Product Name: ethyl (2-(3-hydroxy-3-methylbut-1-yn-1-yl)phenyl)carbamate
• Synonyms: ethyl (2-(3-hydroxy-3-methylbut-1-yn-1-yl)phenyl)carbamate
• CAS NO: 1448422-99-8
• Molecular Weight: 247.294
• Mol File: 1448422-99-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ethyl (2-(3-hydroxy-3-methylbut-1-yn-1-yl)phenyl)carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl (2-(3-hydroxy-3-methylbut-1-yn-1-yl)phenyl)carbamate(1448422-99-8)
• EPA Substance Registry System: ethyl (2-(3-hydroxy-3-methylbut-1-yn-1-yl)phenyl)carbamate(1448422-99-8)

Safety Data

• Hazardous Substances Data: 1448422-99-8(Hazardous Substances Data)

Upstream product

• 104919-70-2 ethyl (2-bromophenyl)carbamate 
• 115-19-5 2-methyl-but-3-yn-2-ol 
• 98952-64-8 N-ethoxycarbonyl-2-iodoaniline 

Downstream Products

• 148550-52-1 ethyl N-(2-ethynylphenyl)carbamate 

Relevant articles and documents

Bi(OTf)3-catalyzed tandem Meyer-Schuster rearrangement and 1,4-addition to the resulting vinyl ketone

Bi(OTf)3-catalyzed Meyer-Schuster rearrangement of electron-rich propargyl alcohols, followed by 1,4-addition of the resulting vinyl ketone, proceeded smoothly though Meyer-Schuster rearrangement of primary propargyl alcohols is rare. This tandem reaction can be extended to an intramolecular version, featuring a one-pot dihydroquinolone synthesis. (Chemical Equation Presented).