144899-38-7

Basic information

• Product Name: DL-3-Amino-2-methyl-4-phenyl-2-butanol
• Synonyms: DL-3-Amino-2-methyl-4-phenyl-2-butanol
• CAS NO: 144899-38-7
• Molecular Weight: 179.262
• Mol File: 144899-38-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: DL-3-Amino-2-methyl-4-phenyl-2-butanol(CAS DataBase Reference)
• NIST Chemistry Reference: DL-3-Amino-2-methyl-4-phenyl-2-butanol(144899-38-7)
• EPA Substance Registry System: DL-3-Amino-2-methyl-4-phenyl-2-butanol(144899-38-7)

Safety Data

• Hazardous Substances Data: 144899-38-7(Hazardous Substances Data)

Upstream product

• 150-30-1 Phenylalanine 
• 75-16-1 methylmagnesium bromide 
• 5619-07-8 methyl 2-amino-3-phenylpropanoate hydrochloride 
• 917-64-6 methyl magnesium iodide 

Downstream Products

• 352438-06-3 4-benzyl-5,5-dimethyloxazolidin-2-one 
• 860312-72-7 tert-butyl (3-hydroxy-3-methyl-1-phenylbutan-2-yl)carbamate 
• 126421-30-5 DL-3-Azido-3-methyl-1-phenyl-2-butanamine 
• 126376-27-0 DL-3-Methyl-1-phenyl-2,3-butanediamine 
• 126376-21-4 DL-3-Benzyl-2,2-dimethylaziridine 

Relevant articles and documents

Controllable Intramolecular Unactivated C(sp3)-H Amination and Oxygenation of Carbamates

Dual catalyst-controlled intramolecular unactivated C(sp3)-H amination and oxygenation of carbamates merging visible-light photocatalysis and earth-abundant transition metal catalysis have been reported. Useful amino alcohol and diol derivatives could be selectively obtained from readily available tertiary alcohol derivatives. The possible mechanisms have been proposed via a 1,5-HAT process followed by Lewis acid-controlled cyclization. The nickel and zinc catalysts inhibit the formation of oxygenation and amination products, respectively. An interesting phenomenon of chirality transfer is also observed.