14492-08-1

Basic information

• Product Name: 1-Piperidinamine, N-[(4-methoxyphenyl)methylene]-
• CAS NO: 14492-08-1
• Molecular Formula: C13H18N2O
• Molecular Weight: 218.299
• Mol File: 14492-08-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-Piperidinamine, N-[(4-methoxyphenyl)methylene]-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Piperidinamine, N-[(4-methoxyphenyl)methylene]-(14492-08-1)
• EPA Substance Registry System: 1-Piperidinamine, N-[(4-methoxyphenyl)methylene]-(14492-08-1)

Safety Data

• Hazardous Substances Data: 14492-08-1(Hazardous Substances Data)

Upstream product

• 110-89-4 piperidine 
• 2213-43-6 1-Aminopiperidine 
• 123-11-5 4-methoxy-benzaldehyde 

Downstream Products

• 112081-06-8 6-(p-Methoxy-phenyl)-5-piperidino-1,3-di(p-tolylsulfonyl)hexahydro-1,3,5-triazin-2,4-dion 
• 112081-05-7 6-(p-Methoxy-phenyl)-1,3-di-methylsulfonyl-5-piperidino-hexahydro-1,3,5-triazin-2,4-dion 

Relevant articles and documents

Continuous Flow α-Arylation of N,N-Dialkylhydrazones under Visible-Light Photoredox Catalysis

The first direct α-arylation of aldehyde-derived N,N-dialkylhydrazones with electron deficient aryl and heteroaryl cyanides under visible-light photoredox catalysis has been developed. Structurally complex α,α′-diaryl-N,N-cycloalkylhydrazones were obtaine

Aza-enamines, VIII. - Electrophilic Substitution reactions at the Azomethine C-Atom of Aldehyde Dialkylhydrazones: Vilsmeier Formylation and Consecutive Reactions

The reaction of hydrazones 1 with the Vilsmeier reagent yields 3-phenyl-1,4,5-triaza-1,3-pentadienium salts according to their aza-enamine character.Hydrolysis of 2 gives 1-phenylglyoxal 1-dialkylhydrazones 3, which rearrange in acidic media to 1-phenylglyoxal 2-dialkylhydrazones 4.Compound 3h forms the dihydropyrroloimidazole 5 in boiling ethanol.Pyrrolotriazinium salt 6 is obtained by the reaction of 1b with the isolated Vilsmeier reagent from dimethylformamide/oxalyl chloride.