144985-28-4

Basic information

• Product Name: Acetic acid (4aR,6S,7R,8S,8aS)-8-allyloxy-6-[(2R,3S,4S,5R,6S)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-((3R,4S,5R,6R)-4,5,6-tris-benzyloxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yloxy]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester
• Synonyms: Acetic acid (4aR,6S,7R,8S,8aS)-8-allyloxy-6-[(2R,3S,4S,5R,6S)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-((3R,4S,5R,6R)-4,5,6-tris-benzyloxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yloxy]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester
• CAS NO: 144985-28-4
• Molecular Weight: 1185.37
• Mol File: 144985-28-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Acetic acid (4aR,6S,7R,8S,8aS)-8-allyloxy-6-[(2R,3S,4S,5R,6S)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-((3R,4S,5R,6R)-4,5,6-tris-benzyloxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yloxy]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid (4aR,6S,7R,8S,8aS)-8-allyloxy-6-[(2R,3S,4S,5R,6S)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-((3R,4S,5R,6R)-4,5,6-tris-benzyloxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yloxy]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester(144985-28-4)
• EPA Substance Registry System: Acetic acid (4aR,6S,7R,8S,8aS)-8-allyloxy-6-[(2R,3S,4S,5R,6S)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-((3R,4S,5R,6R)-4,5,6-tris-benzyloxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yloxy]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester(144985-28-4)

Safety Data

• Hazardous Substances Data: 144985-28-4(Hazardous Substances Data)

Upstream product

• 144985-16-0 2,2-Dimethyl-propionic acid (2R,3R,4S,5R)-2,4-bis-benzyloxy-5-((2S,3R,4S,5R,6R)-3,5-bis-benzyloxy-6-benzyloxymethyl-4-hydroxy-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl ester 
• 144985-15-9 methyl 2-O-acetyl-3-O-allyl-4,6-O-benzylidene-1-thio-β-D-galactopyranoside 
• 145661-97-8 (2R,3R,4S,5R,6S)-3,5-Bis-benzyloxy-2-benzyloxymethyl-6-((3R,4S,5R,6R)-4,5,6-tris-benzyloxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-ol 
• 144985-21-7 Acetic acid (2R,3R,4S,5S,6R)-4-allyloxy-5-benzyloxy-6-benzyloxymethyl-2-chloro-tetrahydro-pyran-3-yl ester 
• 145661-95-6 Acetic acid (2S,3R,4S,5S,6R)-4-allyloxy-5-benzyloxy-6-benzyloxymethyl-2-((3R,4S,5R,6R)-4,5,6-tris-benzyloxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-3-yl ester 
• 145661-94-5 (2S,3aR,6R,7S,7aR)-6-Allyloxy-2,7-bis-benzyloxy-2-methyl-tetrahydro-[1,3]dioxolo[4,5-b]pyran 
• 136136-35-1 benzyl 4-O-allyl-2,3-di-O-benzyl-β-D-xylopyranoside 
• 100-39-0 benzyl bromide 
• 136233-08-4 benzyl 2,3-di-O-benzyl-β-D-xylopyranoside 
• 4163-60-4 β-D-galactose peracetate 
• 55722-48-0 methyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-galactopyranoside 
• 3150-20-7 4-methoxyphenyl β-D-galactopyranoside 
• 155-30-6 methyl 1-thio-β-D-galactopyranoside 
• 144985-26-2 2,2-Dimethyl-propionic acid (2R,3R,4S,5R)-5-((2S,3R,4S,5S,6R)-3-acetoxy-4-allyloxy-5-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-2,4-bis-benzyloxy-tetrahydro-pyran-3-yl ester 

Downstream Products

• 144985-29-5 (4aR,6S,7R,8S,8aR)-7-Benzyloxy-6-[(2R,3S,4S,5R,6S)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-((3R,4S,5R,6R)-4,5,6-tris-benzyloxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yloxy]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol 
• 144985-29-5 (2S,4aR,6S,7R,8S,8aR)-7-Benzyloxy-6-[(2R,3S,4S,5R,6S)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-((3R,4S,5R,6R)-4,5,6-tris-benzyloxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yloxy]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol 

Relevant articles and documents

SYNTHESIS OF SULFATED GLYCOHEXAOSE OF LINKAGE REGION OF CHONDROITIN 4-SULFATE: β-D-GlcA-(1->3)((SO3Na->4))-β-D-GalNAc-(1->4)-β-D-GlcA-(1->3)-β-D-Gal-(1->3)-β-D-Gal-(1->4)-D-Xyl

Stereocontrolled synthesis of glycohexaoses 3 and 4 which corresponds to the linkage region of chondroitin 4-sulfate to a core protein was achieved for the first time by employing glycotriosyl donor 5 and glycotriosyl acceptor 6.