145014-11-5

Basic information

• Product Name: tert-Butyl-((2E,6E,10E,14E)-3,7,11,15,19-pentamethyl-icosa-2,6,10,14,18-pentaenyloxy)-diphenyl-silane
• Synonyms: tert-Butyl-((2E,6E,10E,14E)-3,7,11,15,19-pentamethyl-icosa-2,6,10,14,18-pentaenyloxy)-diphenyl-silane
• CAS NO: 145014-11-5
• Molecular Weight: 597.012
• Mol File: 145014-11-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: tert-Butyl-((2E,6E,10E,14E)-3,7,11,15,19-pentamethyl-icosa-2,6,10,14,18-pentaenyloxy)-diphenyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: tert-Butyl-((2E,6E,10E,14E)-3,7,11,15,19-pentamethyl-icosa-2,6,10,14,18-pentaenyloxy)-diphenyl-silane(145014-11-5)
• EPA Substance Registry System: tert-Butyl-((2E,6E,10E,14E)-3,7,11,15,19-pentamethyl-icosa-2,6,10,14,18-pentaenyloxy)-diphenyl-silane(145014-11-5)

Safety Data

• Hazardous Substances Data: 145014-11-5(Hazardous Substances Data)

Upstream product

• 6784-45-8 (2E,6E)-farnesyl chloride 
• 145014-10-4 (2E,6E,10E)-1-tert-butyldiphenylsiloxy-3,7,11,15-tetramethylhexadeca-2,6,10,14-tetraene 
• 106-24-1 Geraniol 
• 5389-87-7 1-chloro-3,7-dimethylocta-2,6-diene 
• 145014-09-1 (Δ^2,3E,Δ^6,7E)-8-bromo-1-O-tert-butyldiphenylsilyl-3,7-dimethyl-octa-2,6-dien-1-ol 
• 117638-13-8 (Δ^2,3E,Δ^6,7E)-1-O-tert-butyldiphenylsilyl-3,7-dimethyl-octa-2,6-dien-1,8-diol 
• 139109-03-8 tert-butyl ({[(2E)-3,7-dimethylocta-2,6-dien-1-yl]oxy})diphenylsilane 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 22488-05-7 geranylfarnesol 

Relevant articles and documents

Alkene substituents for selective activation of endo-regioselective polyepoxide oxacyclizations

(Chemical equation presented) The presence of an alkenyl substituent on the terminal epoxide of a polyepoxide substrate enhances the yield of all-endo-regioselective tandem oxacyclization to trans-syn-trans-fused polycyclic ethers. For a substrate in which the epoxide and alkene functional groups are separated by two methylene substituents, a novel bromonium ion-induced endo-regioselective cyclization to bromooxepane is also described.