145028-31-5

Basic information

• Product Name: 1,2,3,4-tetrahydro-6-methoxy-1-(3-methoxybenzyl)-2-pivaloylisoquinoline
• CAS NO: 145028-31-5
• Molecular Weight: 367.488
• Mol File: 145028-31-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,2,3,4-tetrahydro-6-methoxy-1-(3-methoxybenzyl)-2-pivaloylisoquinoline(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2,3,4-tetrahydro-6-methoxy-1-(3-methoxybenzyl)-2-pivaloylisoquinoline(145028-31-5)
• EPA Substance Registry System: 1,2,3,4-tetrahydro-6-methoxy-1-(3-methoxybenzyl)-2-pivaloylisoquinoline(145028-31-5)

Safety Data

• Hazardous Substances Data: 145028-31-5(Hazardous Substances Data)

Upstream product

• 145028-30-4 1,2,3,4-tetrahydro-6-methoxy-2-pivaloylisoquinoline 
• 824-98-6 m-methoxybenzyl chloride 
• 42923-77-3 6-methoxy-1,2,3,4-tetrahydro-isoquinoline 
• 3282-30-2 pivaloyl chloride 

Relevant articles and documents

The electrochemical oxidation of aromatic ethers. Part 12. The anodic oxidation of 1,4-dihydro-6,7-dimethoxy-4-(3,4-dimethoxybenzyl)-2-methylisoquinolin -3(2H)-one and attempts to synthesise 2-acyl-4-benzyl-1,2,3,4-tetrahydroisoquinolines through the C-4 alkylation of tricarbonyl η6-1,2,3,4-tetrahydroisoquinoline chromium (0) complexes

We have reinvestigated the anodic oxidation of 1,4-dihydro-6,7-dimethoxy-4-(3,4-dimethoxybenzyl)-2-methylisoquinolin -3(2H)-one and found it to yield a new product: 2,3,7,9-tetramethoxy-11-(N-methylacetamido)dibenzo[a,e]cycloheptatrie n-5-one. In order to investigate reactions of this type 2-acyl-6,7-dimethoxy-4-(3,4-dimethoxybenzyl)-1,2,3,4-tetrahydroisoqui nolines were required. Attempts to synthesise these compounds from the chromium tricarbonyl complexes of 2-acyl-6,7-dimethoxy-1,2,3,4-tetrahydroisoquinolines have failed, leading instead to 2-acyl-1,4-dibenzyl-6,7-dimethoxy-1,2,3,4-tetrahydroisoquinolines.