145049-20-3Relevant articles and documents
Cyclization reactions of β,β-difluoroalkyl radicals (-CF2-C·) for synthesizing gem-difluorocyclic compounds
Morikawa,Kodama,Uchida,Takano,Washio,Taguchi
, p. 8915 - 8926 (2007/10/02)
Cyclization reactions of β,β-difluoroalkyl radicals were carried out. 5 or 6-Exo selective radical cyclizations gave gem-difluorocyclopentane or -cyclohexane derivatives in 53-96% yields. 2,5-Disubstituted-3,3-difluorotetrahydropyran derivatives were prep