1450732-52-1

Basic information

• Product Name: N-tert-butoxy-4-chlorobenzamide
• Synonyms: N-tert-butoxy-4-chlorobenzamide
• CAS NO: 1450732-52-1
• Molecular Weight: 272.142
• Mol File: 1450732-52-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-tert-butoxy-4-chlorobenzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-tert-butoxy-4-chlorobenzamide(1450732-52-1)
• EPA Substance Registry System: N-tert-butoxy-4-chlorobenzamide(1450732-52-1)

Safety Data

• Hazardous Substances Data: 1450732-52-1(Hazardous Substances Data)

Upstream product

• 586-76-5 4-Bromobenzoic acid 
• 39684-28-1 O-(tert-butyl)hydroxylamine hydrochloride 
• 586-75-4 4-chlorobenzoyl chloride 

Downstream Products

• 59247-47-1 tert-butyl-4-bromobenzoate 

Relevant articles and documents

Direct conversion of N -alkoxyamides to carboxylic esters through tandem nbs-mediated oxidative homocoupling and thermal denitrogenation

Treatment of N-alkoxyamides with NBS in toluene was found to conveniently afford the corresponding carboxylic esters, including those bearing a bulky or long-chain substituent, in satisfactory to excellent yields. This approach not only represents a convenient and economic approach to a direct transformation of an alkoxyamide moiety into the carboxylic ester functional group, via oxidative homocoupling and the subsequent thermal denitrogenation, but also facilitates the synthesis of sterically hindered carboxylic esters.