145102-57-4

Basic information

• Product Name: ((3-(but-3-en-1-yl)cyclohex-1-en-1-yl)oxy)trimethylsilane
• Synonyms: ((3-(but-3-en-1-yl)cyclohex-1-en-1-yl)oxy)trimethylsilane
• CAS NO: 145102-57-4
• Molecular Weight: 224.418
• Mol File: 145102-57-4.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: ((3-(but-3-en-1-yl)cyclohex-1-en-1-yl)oxy)trimethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: ((3-(but-3-en-1-yl)cyclohex-1-en-1-yl)oxy)trimethylsilane(145102-57-4)
• EPA Substance Registry System: ((3-(but-3-en-1-yl)cyclohex-1-en-1-yl)oxy)trimethylsilane(145102-57-4)

Safety Data

• Hazardous Substances Data: 145102-57-4(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 930-68-7 cyclohexenone 
• 106-95-6 allyl bromide 
• 31729-70-1 bis(iodozinc)methane 
• 5162-44-7 1-bromo-4-butene 
• 7103-09-5 4-but-1-enylmagnesium bromide 
• 108-94-1 cyclohexanone 

Downstream Products

• 3636-03-1 3-(3-butenyl)cyclohexan-1-one 
• 22627-45-8 3-(3-butenyl)cyclohex-2-en-1-one 
• 1352617-40-3 C₁₉H₂₉NO₂ 
• 1352617-22-1 1-(azaadamantane-N-oxyl)-1-trimethylsilyloxy-3-(3-butenyl)cyclohex-2-ene 
• 130660-18-3 3-(4-Iodobutyl)cyclohexan-1-one 
• 90976-56-0 1-(4-Brom-butyl)-cyclohexanon-⁽³⁾ 

Relevant articles and documents

1,4-Addition reactions of bis(iodozincio)methane with α,β-unsaturated ketones

A reaction of bis(iodozincio)methane with acyclic enones proceeded in 1,4-addition manner to afford zinc enolate of β-zinciomethylketone. In the case of the 1,4-addition reactions of bis(iodozincio)methane with 2- cyclohexen-1-one, an assistance by copper

Synthesis of medium-sized bicyclic compounds by intramolecular cyclization of cyclic β-keto radicals generated from cyclopropanols using manganese(III) tris(pyridine-2-carboxylate) and its application to total synthesis of 10-isothiocyanatoguaia-6-ene

Bicyclic cyclopropanols having an olefinic side chain are oxidized-with manganese(III) tris(pyridine-2-carboxylate) to generate cyclic β-keto radicals with ring-expansion. These cyclize intramolecularly, affording bicyclic radical intermediates. The cycli

Synthesis of cyclopropyl silyl ethers and their facile ring opening by photoinduced electron transfer as key step in radical/radical cationic cascade reactions

Various ring-fused cyclopropyl silyl ethers with an benzylic, olefinic or acetylenic side chain have been synthesized. Upon oxidative photoinduced electron transfer (PET) the cyclopropane ring opens and forms a reactive β-keto radical, which undergoes intramolecular cyclization. In some cases we observed only formation of ring opened non-cyclized products. With olefinic side chain 5-exo-trig mode of cyclization rather than 6-endo-trig mode of cyclization takes place whereas in case of acetylenic side chain we observed 6-endo cyclization.