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14523-22-9

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14523-22-9 Usage

Description

Rhodium carbonyl chloride, also known as tricarbonylchlororhodium, is a transition metal compound with the chemical formula Rh(CO)Cl(PPh3)2. It is a red to brownish crystalline powder that exhibits unique chemical properties and is widely utilized in various industrial applications due to its catalytic and reagent capabilities.

Uses

1. Used in Organic Synthesis:
Rhodium carbonyl chloride is used as a catalyst for various organic reactions, facilitating the formation of complex organic molecules with high efficiency and selectivity. Its catalytic properties make it a valuable component in the synthesis of pharmaceuticals, agrochemicals, and other specialty chemicals.
2. Used in Rhodium-Catalyzed [4+2+1] Cycloaddition:
Rhodium carbonyl chloride is used as a reagent in the rhodium-catalyzed [4+2+1] cycloaddition of in situ generated ene/yne-ene-allenes and carbon monoxide to produce [4+2+1] cycloadducts. This reaction is an important method for constructing complex molecular structures, particularly in the synthesis of natural products and advanced materials.

Reaction

Catalyst used for a wide range of cycloadditions reactions.

Check Digit Verification of cas no

The CAS Registry Mumber 14523-22-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,5,2 and 3 respectively; the second part has 2 digits, 2 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 14523-22:
(7*1)+(6*4)+(5*5)+(4*2)+(3*3)+(2*2)+(1*2)=79
79 % 10 = 9
So 14523-22-9 is a valid CAS Registry Number.
InChI:InChI=1/4CO.2ClH.2Rh/c4*1-2;;;;/h;;;;2*1H;;/q;;;;;;2*+1/p-2

14523-22-9 Well-known Company Product Price

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  • Alfa Aesar

  • (10547)  Tetracarbonyldi-μ-chlorodirhodium(I), Rh 50.1-52.9%   

  • 14523-22-9

  • 0.25g

  • 1348.0CNY

  • Detail
  • Alfa Aesar

  • (10547)  Tetracarbonyldi-μ-chlorodirhodium(I), Rh 50.1-52.9%   

  • 14523-22-9

  • 1g

  • 5189.0CNY

  • Detail
  • Aldrich

  • (209031)  Di-μ-chloro-tetracarbonyldirhodium(I)  97%

  • 14523-22-9

  • 209031-250MG

  • 1,269.45CNY

  • Detail
  • Aldrich

  • (209031)  Di-μ-chloro-tetracarbonyldirhodium(I)  97%

  • 14523-22-9

  • 209031-1G

  • 4,894.11CNY

  • Detail

14523-22-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name Rhodium carbonyl chloride

1.2 Other means of identification

Product number -
Other names Rhodium carbonyl chloride

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:14523-22-9 SDS

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