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14523-89-8

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14523-89-8 Usage

Physical State

Colorless, flammable liquid

Odor

Sweet

Primary Use

Production of synthetic rubber

Secondary Uses

a. Solvent
b. Chemical intermediate in the production of other compounds

Hazard Classification

Hazardous substance

Health Risks

a. Known carcinogen
b. Potential harmful effects on the respiratory system
c. Potential harmful effects on the skin
d. Potential harmful effects on the eyes

Safety Measures

Proper safety measures should be taken when handling and using this chemical.

Check Digit Verification of cas no

The CAS Registry Mumber 14523-89-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,5,2 and 3 respectively; the second part has 2 digits, 8 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 14523-89:
(7*1)+(6*4)+(5*5)+(4*2)+(3*3)+(2*8)+(1*9)=98
98 % 10 = 8
So 14523-89-8 is a valid CAS Registry Number.
InChI:InChI=1/2C4H5Cl/c2*1-3-4(2)5/h2*3H,1-2H2

14523-89-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-chlorobuta-1,3-diene

1.2 Other means of identification

Product number -
Other names 2-Chloro-1,3-butadiene dimer

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:14523-89-8 SDS

14523-89-8Relevant articles and documents

Addition of Chloroprene Grignards to Aromatic Aldehydes: Synthesis of Homoallenyl Alcohols

Geissler, Arne G. A.,Breit, Bernhard

supporting information, p. 2621 - 2625 (2021/04/12)

A general procedure for the one-pot synthesis of racemic homoallenyl alcohols from the corresponding aldehyde and chloroprene-derived Grignards is described. Employing bis[2-dimethylaminoethyl]ether (BDMAEE) as an additive at low temperatures shifts the selectivity of the chloroprene Grignard addition to aldehydes such that it is almost exclusive toward allene formation. In a set of follow-up experiments, simple and more elaborate methods for further derivatization have been demonstrated, allowing quick access to more complex structures.

Thermal ring opening of 1,1-dibromo and 1-bromo-2- chloromethylcyclopropanes: Observation of a formal debromochlorination

Sydnes, Leiv K.,Alnes, Karl F. S.,Pettersen, Anita,Brinker, Udo H.

experimental part, p. 479 - 483 (2010/06/16)

When the title compounds are thermolyzed in the gas phase under vacuum or in hot quinoline, several products are formed. A predominant product in all cases is a chlorine-free buta-1,3-diene which has been formed by formal debromochlorination, a reaction n

Synthesis of the potent anticancer agents ottelione A and ottelione B in both racemic and natural optically pure forms

Clive, Derrick L. J.,Liu, Dazhan

, p. 3078 - 3087 (2008/09/19)

(Chemical Equation Presented) The powerful antitumor agents ottelione A and B were synthesized in racemic form by a method that relies on selective ring closing metathesis. Optically pure natural (+)-ottelione A was then made from D-ribose, via an α-keto cyclopropane. A key feature of the route is that the cyclopropyl group controls the stereochemistry in the attachment of the ArCH2 unit and is then converted by the action of SmI2 into a vinyl group, so that the substituents on the resulting five-membered ring have the required trans relationship. Epimerization of an intermediate gave access by the same method to the trans ring fused isomer (-)-ottelione B.

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