1453111-14-2

Basic information

• Product Name: 2-trimethylsilyl-1,3,3-trimethylcyclohexene
• CAS NO: 1453111-14-2
• Molecular Weight: 196.408
• Mol File: 1453111-14-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-trimethylsilyl-1,3,3-trimethylcyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-trimethylsilyl-1,3,3-trimethylcyclohexene(1453111-14-2)
• EPA Substance Registry System: 2-trimethylsilyl-1,3,3-trimethylcyclohexene(1453111-14-2)

Safety Data

• Hazardous Substances Data: 1453111-14-2(Hazardous Substances Data)

Upstream product

• 1453111-19-7 C₉H₁₆Br₂ 
• 1453111-17-5 1,1-dichloro-2,2,6-trimethylcyclohexane 
• 189633-82-7 2,2,6-trimethyl-cyclohexanone hydrazone 

Relevant articles and documents

Synthesis of five-and six-membered 1,3,3-trimethyl-2-(trimethylsilyl) cycloalkenes: A novel preparation of alkyl/alkenyl/aryl 2,5,5-trimethyl-1- cyclopentenyl ketones

1,3,3-trimethyl-2-(trimethylsilyl)cyclopentene and 1,3,3-trimethyl-2- -(trimethylsilyl)cyclohexene were prepared in good yields by the Wurtz-Fittig coupling reaction of the corresponding 2-iodo-1,3,3-trimethylcyclopentene and 2-chloro-1,3,3-trimethylcyclohexene with metallic sodium and chlorotrimethylsilane in anhydrous ether solvent. The Friedel-Crafts acylation reaction of 1,3,3-trimethyl-2-(trimethylsilyl)cyclopentene with six different acid chlorides and the novel preparation of six alkyl/alkenyl/aryl 2,5,5-trimethyl-1-cyclopentenyl ketones are reported.