145383-38-6Relevant articles and documents
Acid-Catalyzed O-Glycosylation with Stable Thioglycoside Donors
Lacey, Kristina D.,Quarels, Rashanique D.,Du, Shaofu,Fulton, Ashley,Reid, Nicholas J.,Firesheets, Austin,Ragains, Justin R.
supporting information, p. 5181 - 5185 (2018/09/12)
Two classes of thioglycoside, 4-(4-methoxyphenyl)-3-butenylthioglycosides (MBTGs) and 4-(4-methoxyphenyl)-4-pentenylthioglycosides (MPTGs), undergo acid-catalyzed O-glycosylations with a range of sugar and nonsugar alcohols at 25 °C. Electron density at t
S-benzimidazolyl glycosides as a platform for oligosaccharide synthesis by an active-latent strategy
Hasty, Scott J.,Kleine, Matthew A.,Demchenko, Alexei V.
supporting information; experimental part, p. 4197 - 4201 (2011/07/07)
Doing the Biz: The S-benzimidazolyl (SBiz) anomeric moiety is a new leaving group that can be activated for glycosylation under a variety of conditions, including metal-assisted and alkylation pathways. Application of a substituted SBiz moiety (X=anisoyl, see picture) allows active-latent and armed-disarmed types of oligosaccharide assembly. Copyright
Chemoselective synthesis of oligosaccharides of 2-deoxy-2-aminosugars
Bongat, Aileen F. G.,Kamat, Medha N.,Demchenko, Alexei V.
, p. 1480 - 1483 (2007/10/03)
(Chemical Equation Presented) Along with the application of the S-benzoxazolyl glycosides to the high-yielding synthesis of disaccharides of the 2-amino-2-deoxy series, chemoselective assembly of oligosaccharides containing multiple residues of 2-amino-2-