145654-02-0Relevant articles and documents
Total synthesis of chelerythrine, a benzo[c]phenanthridine alkaloid
Ishii,Ishikawa,Takeda,Suzuki,Harayaya
, p. 2002 - 2006 (2007/10/02)
By taking advantage of our novel synthetic methods involving CsF-mediated Claisen rearrangement of an aryl propargyl ether to a 2-methylbenzolfuran and oxidative cleavage of the furan ring to a salicylaldehyde, total synthesis of chelerythrine, a benzo[c]phenanthridine alkaloid, was accomplished via the common intermediate (5) prepared through the two routes shown in Chart 3.