14566-86-0

Basic information

• Product Name: Cadmium,bis(dibutylcarbamodithioato-kS,kS')-, (T-4)- (9CI)
• Synonyms: Cadmium,bis(dibutylcarbamodithioato-S,S')-, (T-4)-; Cadmium,bis(dibutyldithiocarbamato)- (8CI); Carbamodithioic acid, dibutyl-, cadmiumcomplex; Bis(dibutyldithiocarbamato)cadmium; Cadmium dibutyldithiocarbamate
• CAS NO: 14566-86-0
• Molecular Formula: C18H36 Cd N2 S4
• Molecular Weight: 521.171
• Mol File: 14566-86-0.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 257.7°Cat760mmHg
• Flash Point: 109.6°C
• Density: g/cm³
• CAS DataBase Reference: Cadmium,bis(dibutylcarbamodithioato-kS,kS')-, (T-4)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Cadmium,bis(dibutylcarbamodithioato-kS,kS')-, (T-4)- (9CI)(14566-86-0)
• EPA Substance Registry System: Cadmium,bis(dibutylcarbamodithioato-kS,kS')-, (T-4)- (9CI)(14566-86-0)

Safety Data

• Hazardous Substances Data: 14566-86-0(Hazardous Substances Data)

Upstream product

• 2391-80-2 Di-n-butylammonium di-n-butyldithiocarbamate 
• 10108-64-2 cadmium(II) chloride 

Relevant articles and documents

Kinetic analysis of the decomposition of chelates of di-alkyldithiocarbamate of Cd(II)

The thermal decomposition kinetics of the solid complexes Cd(S2CNR2)2, where R=C2H5, n-C3H7, n-C4H9 or iso-C4H9, was studied by using isothermal and non-isothermal thermogravimetry. The super-imposed TG/DTG/DSC curves revealed that thermal decomposition reactions occur in the liquid phase. The kinetic model that best fitted the experimental isothermal TG data was the one-dimensional phase-boundary reaction-controlled process R1. The thermal analysis data suggested the thermal stability sequence Cd(S2CNBu2n)2>Cd(S2CNPr2n)2 >Cd(S2CNBu2i)2>Cd(S2CNEt2)2, which accords with the sequence of stability of the apparent activation energies.

Metal-sulphur Bond Enthalpy Determination of Di-n-Butyldithiocarbamate Chelates of Zinc, Cadmium and Mercury

The standard molar enthalpies of formation of crystalline n2)2> (M = Zn, Cd or Hg), determined through reaction-solution calorimetry at 298.15 K, were found to be -471.23 +/- 3.90, -440.74 +/- 3.79 and -319.29 +/- 3.38 kJ mol-1, respectively.The corresponding molar enthalpies of sublimation, 107 +/- 3, 123 +/- 3 and 195 +/- 3 kJ mol-1, were estimated by means of differential scanning calorimetry.From the standard molar enthalpies of formation of the gaseous chelates, -364 +/- 5, 318 +/- 5 and -124 +/- 5 kJ mol-1, the homolytic and heterolytic mean metal-sulphur bond enthalpies were calculated.The homolytic enthalpies decrease from zinc to mercury, while the heterolytic values are almost constant.